Abstract:Networks of single‐wall carbon nanotubes (SWCNTs) are covalently functionalized with oxygen‐containing groups. In lower concentration, these functional groups act as stable dopands improving the conductivity of the SWCNT material. In higher concentration however, their role as defects with a certain scattering potential becomes dominant, decreasing the conductivity of the CNT material. These effects lead to a trade‐off in the number of functional groups which has been investigated using time‐dependent sonochem… Show more
“…Furthermore, after 50 minutes, the SWCNTs were further doped with nitric acid, again evidenced by the slight increase of the S 11 peak. This phenomenon is consistent with that of SWCNT networks by nitric acid treatment in ultrasonication, although the maximum conductivity occurred slowly in our work [25] . Nevertheless, some defects were generated as a result of the attack of nitrides [25] so that the resonance effect became obscured.…”
Section: Modulation Of Electronic Structures Of Swcnts By Surfactant supporting
Flexible transparent conducting films (TCFs) were fabricated on a PET substrate by various methods using carbon nanotubes dispersed in organic or water-based solution. Thin multi-walled carbon nanotubes, double-walled carbon nanotubes, and single-walled carbon nanotubes were used to compare the performance for TCFs. Optimal design rules for types of nanotubes, surfactants, the degree of dispersion, and film preparation methods were discussed. The TCFs were characterized by scanning electron microscopy, TGA, Raman, optical absorption spectra, and sheet resistance. The dispersion of CNTs in water and in bisolvent has been tried. A simple acid treatment on the TCF film increased the conductivity by about four times. Doping and functionalization techniques will be further introduced to improve the conductivity of the film.
“…Furthermore, after 50 minutes, the SWCNTs were further doped with nitric acid, again evidenced by the slight increase of the S 11 peak. This phenomenon is consistent with that of SWCNT networks by nitric acid treatment in ultrasonication, although the maximum conductivity occurred slowly in our work [25] . Nevertheless, some defects were generated as a result of the attack of nitrides [25] so that the resonance effect became obscured.…”
Section: Modulation Of Electronic Structures Of Swcnts By Surfactant supporting
Flexible transparent conducting films (TCFs) were fabricated on a PET substrate by various methods using carbon nanotubes dispersed in organic or water-based solution. Thin multi-walled carbon nanotubes, double-walled carbon nanotubes, and single-walled carbon nanotubes were used to compare the performance for TCFs. Optimal design rules for types of nanotubes, surfactants, the degree of dispersion, and film preparation methods were discussed. The TCFs were characterized by scanning electron microscopy, TGA, Raman, optical absorption spectra, and sheet resistance. The dispersion of CNTs in water and in bisolvent has been tried. A simple acid treatment on the TCF film increased the conductivity by about four times. Doping and functionalization techniques will be further introduced to improve the conductivity of the film.
“…Doping can occur by chemisorption or physisorption of molecules, [22,41,65,177,233] ions, [223] functional groups, [234] metals particles, [235] or ionic liquid. [236] The transfer characteristics resulting from unintentional doping effects from oxygen and water vapor in the ambient are shown in Figure 16a.…”
Chemically derived graphene oxide (GO) possesses a unique set of properties arising from oxygen functional groups that are introduced during chemical exfoliation of graphite. Large-area thin-film deposition of GO, enabled by its solubility in a variety of solvents, offers a route towards GO-based thin-film electronics and optoelectronics. The electrical and optical properties of GO are strongly dependent on its chemical and atomic structure and are tunable over a wide range via chemical engineering. In this Review, the fundamental structure and properties of GO-based thin films are discussed in relation to their potential applications in electronics and optoelectronics.
“…Ultrasonication served to impart enough energy to separate the nanoparticles from each other long enough for surfactant to surround the nanoparticles and prevent them from agglomerating [32]. Since excessive sonication causes defect in CNTs [33], the ultrasonication time for both GN and MWCNTs was 20 min. Later, 40 min ultrasonication was performed for GN-SDS nanofluid.…”
High-thermal conductivity enhancement of nanofluid is one of the promising topics of the nanoscience research field. This work reports the experimental study on the preparation of graphene (GN) and multi-walled carbon nanotubes (MWCNTs) based nanofluids with the assistance of sodium dodecyl benzene sulfonate (SDBS) and sodium dodecyl sulfate (SDS) surfactants, and their thermal behaviors. The present work suggests not a solution, but a solution approach and deduces a new conclusion by trying to resolve the agglomeration problem and improve the dispersibility of nanoparticles in the base fluid. The analysis results of FESEM, thermal conductivity, diffusivity, effusivity and heat transfer coefficient enhancement ratio of nanofluid with surfactants SDS and SDBS expose strong evidence of the dispersing effect of surfactant on the making of nanofluid.
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