“…Solar energy has been regarded as the most potential clean and environment-friendly energy source to tackle the increasingly serious energy shortage and environmental pollution. , Developing functional materials for achieving solar energy conversion has attracted much attention among researchers. In recent years, layered orthorhombic bismuth sulfide (Bi 2 S 3 ) has emerged as a kind of promising semiconductors candidate in photocatalysts, , photoelectrochemical (PEC) devices, , sensors, , photovoltaic devices, , thermoelectric devices, , electrochemical energy storage cells, , and photothermal therapy due to its excellent optical and electrical properties such as a relatively narrow band gap and a high absorption coefficient. − Moreover, the nontoxic nature of Bi 2 S 3 endows more competitiveness in green development compared with other metal chalcogenides . In the past decades, numerous reports have been focused on investigating the synthesis and properties of Bi 2 S 3 nanoparticles. ,− From the point of view of practical application, nanoparticles have several drawbacks, such as low reusability and strong light diffusion.…”