Some Historical Developments Relating to Corrosion

Lynes, Wilson

doi:10.1149/1.2778101

Cited by 30 publications

(5 citation statements)

References 6 publications

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“…There is a long history of study for rust prevention and control. , Some organic compounds are effective inhibitors for aqueous corrosion of metals, being adsorbed on the metal surfaces. , Selection of these inhibitors has been based on an empirical approach to date. For proper selection of inhibitors, mechanistic information on corrosion and inhibition processes is needed.…”

Section: Introductionmentioning

confidence: 99%

Theoretical Study of NH₃ Adsorption on Fe(110) and Fe(111) Surfaces

2006

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With the aim of understanding the nature of the interactions between organic molecules and metal surfaces, the adsorption of NH3 onto model Fe(110) and Fe(111) surfaces has been studied with use of the molecular orbital and density functional theories. B3LYP calculations have revealed that the on-top site is most suitable for adsorption of NH3 both on Fe(110) and on Fe(111). Mulliken population analysis in terms of the MO's of the two fragment systems suggested that electron delocalization from NH3 to the Fe surface should play a key role in the adsorption. Then, our transformation scheme of fragment orbitals has demonstrated that the electron delocalization is represented well only by a pair of interaction orbitals. The NH3 molecule provides the occupied interaction orbital bearing a close resemblance to the highest occupied (HO) MO, whereas the Fe surface prepares the paired unoccupied orbital that is localized at the adsorption site and overlaps in-phase with the orbital of NH3. Not only the lowest unoccupied (LU) MO but also other unoccupied MO's have been shown to participate significantly in the interaction. The reason the on-top site is the most preferable position for NH3 attack has been elucidated by investigating the interaction orbitals.

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Section: Introductionmentioning

confidence: 99%

Theoretical Study of NH₃ Adsorption on Fe(110) and Fe(111) Surfaces

2006

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“…Galvanic corrosion occurs between two different metals that come into contact together and are immersed in an electrolyte (also called bimetallic corrosion). 71,72 The electrons will flow from the metal with a lower standard electrode potential (versus the standard hydrogen electrode, SHE) to the metal with a higher standard electrode potential. Therefore, the metal with a lower standard electrode potential will be corroded.…”

Section: Corrosionmentioning

confidence: 99%

“…steel, and carbon fibers) will force Li to undergo galvanic corrosion. 71,72 This process will result in Li ions, leading to the loss of active anode material during storage (Fig. 6c).…”

Section: Corrosionmentioning

confidence: 99%

Shelf life of lithium–sulfur batteries under lean electrolytes: status and challenges

Guo,

Yang,

Dou

et al. 2024

Energy Environ. Sci.

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“…Lynes also compares deductions early in the 20th century with similar ones in the period 1800-1850 regarding oxygen depolarization, differential oxygen concentration cells, differential solution concentration cells, passivity of iron, and the corrosion of iron. 6 Lynes also draws attention to the strong advections to the hypothesis that heterogeneities were the sole cause of corrosion. These ideas continued to be considered throughout the 20th centaury.…”

Section: Items Of Interest From the Society's Publicationsmentioning

confidence: 99%