INTRODUCTIONChlorophenols (CPs) are a class of compounds with benzene ring of phenol connected with chlorine atoms. Chlorophenols as commonly used chemical raw materials, are often used as pesticides, preservatives, herbicides and they are a category of widespread organic contaminants. Because chlorophenols are high toxicity, difficult biodegradation, the carcinogenicity-mutagenicity-teratogenicity and may concentrate through the food chain in organism, have been listed the priority pollutant ranks by environmental protection agency of various countries 1,2 .At present, the detection methods of chlorophenols are mainly high performance liquid chromatography (HPLC) 3 , ultraviolet spectrophotometry (UV) 4 , gas chromatography (GC) 5,6 and gas chromatography-mass spectrometry (GC-MS) 7,8 . The methods of sample preparation are mainly solvent extraction 9 , solid phase extraction 10,11 , solid phase microextraction 12,13 , headspace solid phase extraction 14 , liquid phase microextraction 15 and liquid-liquid extraction 16 .Ionic liquids aqueous two-phase system (ILATPS) is a new system which can be used for extraction of substances in recent years 17 . Li et al. 18 extracted trace roxithromycin in real water samples by use of ionic liquid([Bmim]BF4)-salt(Na2CO3) aqueous two-phase system, the average extraction efficiency is up to 90.7 %. He et al. 19 extracted testosterone and epitestosterone in human urine using aqueous two-phase systems of