Abstract:1-Methyl-1H-tetrazoline-5-thione (1) reacts with iodine in CHCl 3 with formation of 1:1 stable r-complex (logb = 3.8 ± 0.1 is found by spectrophotometry). In the ethanol solution irreversible oxidation with formation of disulfide product 5,5 0 -dithiobis(1-methyl-1H-tetrazole) (2) is observed. The structure of (2) was determined by X-ray diffraction. Strong intermolecular interactions with shortened contacts are observed between sulfur atom of disulfide bridge and heterocyclic nitrogen of the neighboring molec… Show more
“…In the experimental study by Aleshina et al [85], the reaction of 1-methyl-1H-tetrazoline-5-thione with elemental iodine in weakly polar aprotic chloroform and in dipolar amphiprotic ethanol was studied. While a 1:1 stable r-complex was formed in chloroform, 5,5 0 -dithiobis(1-methyl-1H-tetrazole) was obtained from ethanol due to a substantial charge transfer and initiates the formation of the disulfide oxidation product.…”
In the current review of the journal Structural Chemistry, the content of the first three issues for the calendar year 2011 is related to thermochemistry. Each paper is summarized and followed by a short thermochemical comment.
“…In the experimental study by Aleshina et al [85], the reaction of 1-methyl-1H-tetrazoline-5-thione with elemental iodine in weakly polar aprotic chloroform and in dipolar amphiprotic ethanol was studied. While a 1:1 stable r-complex was formed in chloroform, 5,5 0 -dithiobis(1-methyl-1H-tetrazole) was obtained from ethanol due to a substantial charge transfer and initiates the formation of the disulfide oxidation product.…”
In the current review of the journal Structural Chemistry, the content of the first three issues for the calendar year 2011 is related to thermochemistry. Each paper is summarized and followed by a short thermochemical comment.
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