Solvent-induced Zn(II) coordination polymers with 1, 3, 5-benzenetricarboxylic acid

Humidity-Induced Structural Transformation in Pseudopolymorph Coordination Polymers

“…Therefore, the bridging coordination of the acetate anions in compounds 1 and 2 was mainly responsible for obtaining the 1D ladder structural motif. These results highlight the significant role of the solvent in the determination of structural motif CPs. ,,− …”

“…Supramolecular isomers are compounds with the same chemical composition but different structures, supramolecular networks, or topologies. ,, Considering the variety of interactions between the structural motifs and the presence or absence of guest solvent or anion molecules in the supramolecular isomers, they are divided into five categories including structural, optical, catenane, polymorphic, and pseudopolymorphic supramolecular isomers. ,− Among these categories, pseudopolymorphs or solvatomorphs are different in the type or number of guest solvents in the structure. − This point highlights the role of solvent in the construction of supramolecular isomers.…”

Caterpillar-like Ag–ZnO–C hollow nanocomposites for efficient solar photocatalytic degradation and disinfection

“…However, even though BTC possesses three carboxylate groups and one benzene ring beneficial to the multiplicity of MOF structures, due to their lack of size and morphology control, Zn-BTC based MOFs tend to be converted to bulk phase materials featuring a low number of exposed active metal sites. 21 Herein, we present a new and effective strategy to synthesize a hierarchical Ag-ZnO-C (AZC) hybrid hollow nanocomposite comprising plentiful nanorods, nanoparticles and nanosheets. Zn-MOF nanorods were firstly obtained via a reaction between ZnCl 2 and BTC in aqueous solution at room temperature in a short time.…”

Syntheses, crystal structures, and fluorescent properties of three coordination polymers with 5-sulfoisophthalic acid anion and 4-phenylpyridine

“…The intense interest in these materials is driven by their potential applications as functional materials for luminescence sensing, gas storage and separation, drug delivery, catalysis, magnetism, and due to their intriguing structural diversity. [1][2][3][4][5][6] It is well-known that many factors such as synthetic methods, central metals, ligands, and pH can influence the final structures of CPs. [7][8][9][10] There is no doubt that organic ligands and the metal center play a significant role in the design and synthesis of CPs, while selecting the coordination geometry of the metal centers and organic ligands containing appropriate functional groups (such as polycarboxylic acid or multipyridine ligands) are also key for constructing CPs.…”