“…It is reported that organic materials, such as polymers or macromolecules having -OH, -COOH, -NH2, etc., functional groups, were found to be corrosion inhibitors in different corrosive environments. Important corrosion inhibition efficiencies that are observed using conducting polymers are not only due to the presence of π-electrons, but also to their larger molecular size, which ensures greater coverage of the metallic surface [12]. Thus, the efficiency of an organic compound as a successful inhibitor is mainly due to its ability to be adsorbed onto the metal surface.…”
Section: Introductionmentioning
confidence: 99%
“…The initial report of corrosion inhibition by organic inhibitors is attributed to Speller [11], who examined the corrosion inhibition of scaled water pipes in HCl. Since then, many organic and inorganic compounds that are added to corrosive fluids have been investigated for this purpose [10][11][12][13][14][15][16][17][18][19][20][21][22][23]. It is reported that organic materials, such as polymers or macromolecules having -OH, -COOH, -NH2, etc., functional groups, were found to be corrosion inhibitors in different corrosive environments.…”
Section: Introductionmentioning
confidence: 99%
“…Metal corrosion is a major industrial problem, and it has attracted the attention of researchers worldwide [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20]. The use of inhibitors has been found to be one of the best practical methods available for the protection of metals against corrosion, especially in acidic media [8][9]23].…”
Section: Introductionmentioning
confidence: 99%
“…Inhibitors are substances (or a combination of substances) added in a very low concentration to treat the surface of a metal that is exposed to a corrosive environment, in order to terminate or reduce its corrosion rate [8]. The most efficient corrosion inhibitors are organic compounds containing electronegative functional groups and electrons in their triple or conjugated double bonds, and/or inorganic compounds, such as chromate, dichromate, nitrite, and so on [10][11][12][13]. The initial report of corrosion inhibition by organic inhibitors is attributed to Speller [11], who examined the corrosion inhibition of scaled water pipes in HCl.…”
In the present work, the inhibitory properties and the adsorption mechanism of penicillin G for the corrosion of Fe-19Cr stainless steel in an HCl solution were investigated. Electrochemical methods, the open circuit potential (OCP) and the current potential curves (I-V) were used. The inhibition efficiency of the penicillin G was calculated and found to be up to 60% for hydrochloric acid. The adsorption of this inhibitor was described by Langmuir isotherm, and the negative values of Gibbs energy indicate the nature of interactions between the inhibitor molecules and the metal surface.
“…It is reported that organic materials, such as polymers or macromolecules having -OH, -COOH, -NH2, etc., functional groups, were found to be corrosion inhibitors in different corrosive environments. Important corrosion inhibition efficiencies that are observed using conducting polymers are not only due to the presence of π-electrons, but also to their larger molecular size, which ensures greater coverage of the metallic surface [12]. Thus, the efficiency of an organic compound as a successful inhibitor is mainly due to its ability to be adsorbed onto the metal surface.…”
Section: Introductionmentioning
confidence: 99%
“…The initial report of corrosion inhibition by organic inhibitors is attributed to Speller [11], who examined the corrosion inhibition of scaled water pipes in HCl. Since then, many organic and inorganic compounds that are added to corrosive fluids have been investigated for this purpose [10][11][12][13][14][15][16][17][18][19][20][21][22][23]. It is reported that organic materials, such as polymers or macromolecules having -OH, -COOH, -NH2, etc., functional groups, were found to be corrosion inhibitors in different corrosive environments.…”
Section: Introductionmentioning
confidence: 99%
“…Metal corrosion is a major industrial problem, and it has attracted the attention of researchers worldwide [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20]. The use of inhibitors has been found to be one of the best practical methods available for the protection of metals against corrosion, especially in acidic media [8][9]23].…”
Section: Introductionmentioning
confidence: 99%
“…Inhibitors are substances (or a combination of substances) added in a very low concentration to treat the surface of a metal that is exposed to a corrosive environment, in order to terminate or reduce its corrosion rate [8]. The most efficient corrosion inhibitors are organic compounds containing electronegative functional groups and electrons in their triple or conjugated double bonds, and/or inorganic compounds, such as chromate, dichromate, nitrite, and so on [10][11][12][13]. The initial report of corrosion inhibition by organic inhibitors is attributed to Speller [11], who examined the corrosion inhibition of scaled water pipes in HCl.…”
In the present work, the inhibitory properties and the adsorption mechanism of penicillin G for the corrosion of Fe-19Cr stainless steel in an HCl solution were investigated. Electrochemical methods, the open circuit potential (OCP) and the current potential curves (I-V) were used. The inhibition efficiency of the penicillin G was calculated and found to be up to 60% for hydrochloric acid. The adsorption of this inhibitor was described by Langmuir isotherm, and the negative values of Gibbs energy indicate the nature of interactions between the inhibitor molecules and the metal surface.
“…The copolymer shows new morphology with higher thermal stability and better solubility than its homopolymers. Potentiodynamic polarization and electrochemical impedance spectroscopy have been employed to study the corrosion inhibition effects of this copolymer on carbon steel 9 . Recently it has been reported that the metal composite of poly (aniline-co-o-toluidine)-BaFe 12 O 19 composite exhibited a ferro magnetic behavior 10 .…”
Copolymerization of aniline and o-toluidine is achieved by chemical oxidative polymerization with equal molar ratio of monomers in the presence of hydrochloric acid and ammonium persulphate as an oxidant. The copolymer found to be more soluble in polar solvents such as NMP, DMF and DMSO. FTIR spectroscopy confirms the copolymer chemical structure. UV spectroscopy shows π to π* transition and excitonic transition of the copolymer film. The copolymer is doped with camphorsulfonic acid (CSA) in m-cresol and then zinc oxide nanoparticles are dispersed into the copolymer and spin coated on to a glass plate. The scanning electron microscope image shows the morphology of the copolymer matrix. X-ray Diffraction shows the characteristic peaks of CSA and zinc oxide. EDAX analysis confirms the presence of CSA and zinc oxide. The dispersion of zinc oxide nanoparticles show quenching property of photoluminescence indicating that the copolymer can be used in the opto-electronics.
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