Solubility of Dimethyl Fumarate in Methanol, Ethanol, 1-Propanol, 2-Propanol, 1,2-Propanediol, and Water from (289.95 to 347.15) K

Abstract

Using the laser monitoring observation technique, the solubilities of dimethyl fumarate in methanol, ethanol, 1-propanol, 2-propanol, 1,2-propanediol, and water have been determined experimentally from (289.95 to 347.15) K. The experimental data were correlated with the modified Apelblat equation. The calculated results showed good agreement with the experimental data.

Critical Review on Biochar‐Supported Catalysts for Pollutant Degradation and Sustainable Biorefinery

“…[ 3 ] There are numerous original research articles and well‐organized reviews published recently on activation and functionalization of BCs, describing the applications of BCs as catalysts/catalyst supports for environmental application. [ 10,18,19 ] Since this review mainly discusses BC/BC‐supported materials for catalytic removal/degradation of pollutants and biorefinery, therefore, here we focus on activation and functionalization of BCs for promoting these processes (i.e., organic degradation via AOP and biomass valorization).…”

“…In comparison with other approaches, advanced oxidation processes (AOPs) are gaining more attention for removal of organic pollutants in the environment these days. [ 16–18 ] AOPs can generate hydroxyl ( • OH) as well as sulfate (SO 4 •− ) radicals during the degradation, having robust redox potential and enormous reactivity. [ 19–21 ] Principally, AOPs include two types of catalytic processes: i) homogeneous catalysis, including chemical activation of peroxymonosulfate (PMS) as well as peroxydisulfate (PDS), Fenton, [ 19–21 ] photo‐Fenton, [ 22 ] and several other chemical reactions in which oxidizing free radicals are produced, and ii) heterogeneous catalysis such as carbonaceous materials [ 23 ] and nanoscale zero‐valent iron (nZVI), [ 24 ] etc.…”

“…[ 28 ] Due to higher porosity and diverse oxygen‐containing functional groups (OCFGs) such as carboxyl (COOH) and hydroxyl (OH) on its surface, BC can be easily applied to disperse and stabilize the nanoparticles. [ 18,19,24 ] Moreover, the higher specific surface area and better porosity make BC an efficient adsorbent to remove environmental contaminants. [ 3,29 ] Therefore, by using BC‐supported catalysts (e.g., BC‐conjugated nZVI (nZVI/BC), Fe 3 O 4 /BC, and iron‐impregnated‐BC (Fe‐BC)), organic contaminants were effectively degraded via AOPs with improved efficiencies.…”

“…[ 3,29 ] Therefore, by using BC‐supported catalysts (e.g., BC‐conjugated nZVI (nZVI/BC), Fe 3 O 4 /BC, and iron‐impregnated‐BC (Fe‐BC)), organic contaminants were effectively degraded via AOPs with improved efficiencies. [ 18,30,31 ]…”

Guidelines for reporting of phase equilibrium measurements (IUPAC Recommendations 2012)

“…Table 4: (Liquid + liquid) equilibrium data; often termed "tie-line" data [71]. Table 5: (Solid + liquid) equilibrium data; often termed "solubility" data [72]. Table 6: (Solid + liquid) equilibrium data; often termed "SLE phase diagram" data [73].…”