Abstract:The solid−liquid equilibrium of the ternary MgBr 2 −MgSO 4 − H 2 O system at 348.15 K was explored by using the isothermal equilibrium method, intending to realize the comprehensive utilization of the basic magnesium bromide (MgBrOH) waste residue produced in maltol production. It was observed that the phase diagram was composed of four single-salt crystallization regions, four univariate solubility curves, three invariant points saturated with
“…The solid–liquid equilibrium experiments in this work were conducted by the method of isothermal dissolution, and the experimental procedure has also been reported in the previous studies. , The second salt was added into the saturated binary subsystem (NaCl–CH 3 OH–H 2 O or NaBr–CH 3 OH–H 2 O) gradually in different proportions to prepare the ternary mixtures, which were held in several 17 mL test tubes, and the solution accounted for about 2/5 of the tube volume. Then, all the test tubes were sealed tightly with PTFE tapes, fixed on the pallet of an electric motor, and completely submerged in the water.…”
Aiming to improve the utilization of bromine resources in bittern, the solubilities of the ternary NaCl−NaBr−CH 3 OH−H 2 O mixed solvent system at 298 and 323 K were measured by the method of isothermal dissolution equilibrium, and the corresponding phase diagrams were constructed. The results show that the phase diagrams at the two temperatures are similar, and both have only one univariant curve and one crystallization region corresponding to a solid solution Na(Cl, Br) without invariant points. Based on the extended Pitzer model, Pitzer parameters were calculated, and the activity product of the solid solution was regressed into a polynomial of Br − mole fraction in the solid solution. The solubilities of the ternary NaCl−NaBr− CH 3 OH−H 2 O mixed solvent system at 298 K were calculated. The computed results are in accordance with the experimental values.
“…The solid–liquid equilibrium experiments in this work were conducted by the method of isothermal dissolution, and the experimental procedure has also been reported in the previous studies. , The second salt was added into the saturated binary subsystem (NaCl–CH 3 OH–H 2 O or NaBr–CH 3 OH–H 2 O) gradually in different proportions to prepare the ternary mixtures, which were held in several 17 mL test tubes, and the solution accounted for about 2/5 of the tube volume. Then, all the test tubes were sealed tightly with PTFE tapes, fixed on the pallet of an electric motor, and completely submerged in the water.…”
Aiming to improve the utilization of bromine resources in bittern, the solubilities of the ternary NaCl−NaBr−CH 3 OH−H 2 O mixed solvent system at 298 and 323 K were measured by the method of isothermal dissolution equilibrium, and the corresponding phase diagrams were constructed. The results show that the phase diagrams at the two temperatures are similar, and both have only one univariant curve and one crystallization region corresponding to a solid solution Na(Cl, Br) without invariant points. Based on the extended Pitzer model, Pitzer parameters were calculated, and the activity product of the solid solution was regressed into a polynomial of Br − mole fraction in the solid solution. The solubilities of the ternary NaCl−NaBr− CH 3 OH−H 2 O mixed solvent system at 298 K were calculated. The computed results are in accordance with the experimental values.
“…This research not only contributes to future investigations related to amino acids, but also provides valuable insights into optimizing purification and separation techniques and reducing energy consumption. [19][20][21][25][26][27]…”
Amino acids hold significant importance in the diagnosis and treatment of various chronic diseases. Accurate solid-liquid equilibrium data is the key to drug synthesis and chemical production. However, the studies...
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