2013
DOI: 10.1016/j.ijhydene.2013.04.109
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Sodium alanate system for efficient hydrogen storage

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Cited by 48 publications
(27 citation statements)
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“…50 This complex hydride crystallises in the tetragonal space group I4 1 /a (#88), in which the isolated [AlH 4 ] − tetrahedra engage in a multitude of stabilising Na⋯H-Al interactions (2.439-2.456 Å). 50 This complex hydride crystallises in the tetragonal space group I4 1 /a (#88), in which the isolated [AlH 4 ] − tetrahedra engage in a multitude of stabilising Na⋯H-Al interactions (2.439-2.456 Å).…”
Section: Complex Metal Hydridesmentioning
confidence: 99%
“…50 This complex hydride crystallises in the tetragonal space group I4 1 /a (#88), in which the isolated [AlH 4 ] − tetrahedra engage in a multitude of stabilising Na⋯H-Al interactions (2.439-2.456 Å). 50 This complex hydride crystallises in the tetragonal space group I4 1 /a (#88), in which the isolated [AlH 4 ] − tetrahedra engage in a multitude of stabilising Na⋯H-Al interactions (2.439-2.456 Å).…”
Section: Complex Metal Hydridesmentioning
confidence: 99%
“…However, a catalyst can significantly enhance kinetics, heighten the degree of stability, and/or possess more favourable thermodynamic properties [6]. Meanwhile, the reactive hydride composites (RHCs) method is quite a different approach that aims at modifying the thermodynamics and kinetics of the hydrogen sorption reaction by mixing two or more hydrides [7e14].…”
Section: Introductionmentioning
confidence: 99%
“…[10] Since their discovery,alarge number of complexh ydrides have been explored, and some of them have been found to be thermodynamicallyf avorable for on-boarda pplications. [5,11] In 2006, Bogdanović et al demonstrated that compounds of some less-common metals could also be used as highly efficientd opants for NaAlH 4 . [12] In particular, recent results show that dehydrogenated nanocrystalline TiO 2 @Cdoped NaAlH 4 can absorb 4.5 wt %H 2 within 12 min at 80 8Cu nder 100 bar (1 bar = 0.1 MPa) of hydrogen pressure.…”
Section: Introductionmentioning
confidence: 99%