Liquid-crystal microcavity lasers have attracted considerable
attention
because of their extraordinary tunability and sensitive response to
external stimuli, and because they operate generally within a specific
phase. Here, we demonstrate a liquid-crystal microcavity laser operated
in the phase transition in which the reorientation of liquid-crystal
molecules occurs from aligned to disordered states. A significant
wavelength shift of the microlaser is observed, resulting from the
dramatic changes in the refractive index of liquid-crystal microdroplets
during the phase transition. This phase-transition microcavity laser
is then exploited for sensitive thermal sensing, enabling a two-order-of-magnitude
enhancement in sensitivity compared with the nematic-phase microlaser
operated far from the transition point. Experimentally, we demonstrate
an exceptional sensitivity of −40 nm/K and an ultrahigh resolution
of 320 μK. The phase-transition microcavity laser features compactness,
softness, and tunability, showing great potential for high-performance
sensors, optical modulators, and soft matter photonics.