2003
DOI: 10.1016/s0038-1098(03)00675-6
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Single crystal EPR studies of Cu(II) doped in cadmium sodium sulphate hexahydrate: a case of low hyperfine coupling constant

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Cited by 28 publications
(10 citation statements)
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“…A similar observation is known in cases of Mn(II) doped in tris(ethylenediamine) zinc(II) [23], zinc acetate dihydrate [24] and Ca 2 Ba(COOH) 6 [25]. The large observed shift of the g-values from the free ion value for Cu(II) in low symmetry can be well accounted by mixing the excited state into the ground state [26][27][28]. However, the admixtures of the excited quartet levels into the ground state 6 S by spin-orbit coupling produce only a small negative g-shift.…”
Section: Resultssupporting
confidence: 75%
“…A similar observation is known in cases of Mn(II) doped in tris(ethylenediamine) zinc(II) [23], zinc acetate dihydrate [24] and Ca 2 Ba(COOH) 6 [25]. The large observed shift of the g-values from the free ion value for Cu(II) in low symmetry can be well accounted by mixing the excited state into the ground state [26][27][28]. However, the admixtures of the excited quartet levels into the ground state 6 S by spin-orbit coupling produce only a small negative g-shift.…”
Section: Resultssupporting
confidence: 75%
“…For example, the value of the A 33 hyperfine coupling constant is appreciably lower than the value of A || generally found for a copper(II) ion. 11 The …”
mentioning
confidence: 99%
“…These parameters are calculated for Cu(II)/GLS, using powder data and are tabulated in table 5 [28][29][30] with other Cu(II) systems for comparison. This computation is carried out by assuming A || to be negative and A ⊥ to be positive.…”
Section: Resultsmentioning
confidence: 99%