Single- and multi-component adsorption of selected contaminants of emerging concern from water and some of their metabolites onto hierarchical porous copper(II)-zeolite -activated carbon composite

Fernández-Reyes, Bethzaely; Morales-Jiménez, Stefannie; Muñoz-Senmache, Juan C.; Vega-Santander, Dariana R.; Hernández‐Maldonado, Arturo J.

doi:10.1016/j.micromeso.2020.110355

Cited by 11 publications

(6 citation statements)

References 68 publications

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“…Furthermore, it was determined that a thermal treatment prior to the incorporation of the metal breaks the amino/silica interactions and redirect these toward the amino/metal. In addition, they found that lower levels of hydration in the metal salts produced uniform and larger pore size (~80-90 Å), surface area (~375 m 2 g −1 ) and volume as well as larger metal 56] loadings; this is crucial when attempting to address working capacity [52]. The improvements in all the aforementioned factors resulted in enhancement of the equilibrium adsorption capacity for naproxen at neutral pH (see Figure 2).…”

Section: Incorporation Of Transition Metals As Adsorption Sitesmentioning

confidence: 99%

“…There are several techniques that can be utilized for the effective incorporation of transition metals onto an adsorbent structure, including wetness impregnation [45][46][47], spontaneous monolayer dispersion [45,48], grafting [49][50][51][52][53], and ion exchange [54][55][56][57]. Among these, grafting and ion exchange have produced better results with respect to water-stability and loading of metal.…”

Section: Incorporation Of Transition Metals As Adsorption Sitesmentioning

confidence: 99%

“…González-Ramos et al [55]. and Fernández-Reyes et al [56]. have shown that composites prepared hierarchically via in situ growth of FAU into the macro-and meso-pores of activated carbon (AC) (i.e.…”

Section: Hierarchical Composites Via Confined-space Synthesismentioning

confidence: 99%

“…Transition metals (i.e. M = Ni 2+ or Cu 2+ ) were also added to these composites via ion exchange with excess amounts of metal source salts [55,56]. It is important to note at this point of the discussion that, given the significant difference between the bulk density values of the carbon and the zeolite phase (0.31 g cm −3 for AC and around 1.0 g cm −3 for FAU), a comparison of CEC uptake capacities between the hierarchical composites and the source phases entails a basis that is independent of chemical content.…”

Section: Hierarchical Composites Via Confined-space Synthesismentioning

confidence: 99%

“…Data source: Ortiz-Martínez et al [53]. Cabrera-Lafaurie et al [54,62]; Fernández-Reyes et al [56] fashion. The observed single-component fashion adsorption capacities observed for CMOF were an order of magnitude larger compared to MIL-100Fe alone, while the overall capacity was reduced by about 9% when testing for the multi-component CEC adsorption (i.e.…”

Section: Hierarchical Composites Via Confined-space Synthesismentioning

confidence: 99%

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Progress in the design of nanoporous adsorbent materials containing transition metals for the removal of contaminants of emerging concern

Muñoz-Senmache

Fernández-Reyes

Hernández‐Maldonado

2021

Environmental Pollutants and Bioavailability

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Significant attention has been paid to contaminants of emerging concern (CECs) for several years due to their persistence in water sources and toxicity. The necessity of upgrading current wastewater treatment technologies is vital to guarantee timely remediation of CECs, particularly given the scarcity of potable water for direct human consumption and even for agricultural irrigation. In this regard, the integration of transition metals onto porous adsorbent materials for use in water and wastewater treatment operations could play a significant role due to their ability to undergo specific interactions (i.e., complexation-type) with CECs at ambient temperature. Furthermore, coupling these interactions with hydrophobicity inducing species or phases in situ (i.e. hierarchically) further enhances affinity and capacity toward CECs. This review highlights the progress so far in the bench-scale design of transition metal-based nanoporous adsorbents, including hierarchical composites prepared via confined space synthesis, for the removal of CECs from water at ambient conditions.

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Section: Incorporation Of Transition Metals As Adsorption Sitesmentioning

confidence: 99%

Section: Incorporation Of Transition Metals As Adsorption Sitesmentioning

confidence: 99%

Section: Hierarchical Composites Via Confined-space Synthesismentioning

confidence: 99%

Section: Hierarchical Composites Via Confined-space Synthesismentioning

confidence: 99%

Section: Hierarchical Composites Via Confined-space Synthesismentioning

confidence: 99%

See 3 more Smart Citations

Progress in the design of nanoporous adsorbent materials containing transition metals for the removal of contaminants of emerging concern

Muñoz-Senmache

Fernández-Reyes

Hernández‐Maldonado

2021

Environmental Pollutants and Bioavailability

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Tailoring hydrophobicity vs. water capacity of adsorbents for adsorption applications: role of composites

Atalay-Oral,

Tatlier

2024

Adsorption

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Water adsorption capacities of various adsorbents reported in the literature were investigated to define a hydrophobicity index that was plotted vs. water capacity. In this plot, logarithmic curves were proposed to be used as indicators of performance limits of adsorbents, especially for adsorption heat pumps. In spite of their useful adsorption properties, zeolites generally exhibited quite low hydrophobicity, remaining well below the logarithmic curve. In this study, the use of composites of zeolite NaY was examined both theoretically and experimentally for improvements in the water capacity and hydrophobicity. Salt impregnation and hydrothermal synthesis experiments were performed to prepare composites of zeolite NaY with LiCl/MgCl2 salts and activated carbon, respectively. Water capacity and hydrophobicity of zeolite NaY composites were generally superior to those of pure zeolite. Zeolite composites may be advantageous for enhancing adsorption capacity and hydrophobicity of zeolites while eliminating low stability and slow adsorption kinetics of other adsorbents. Interface between two different phases might indicate another opportunity to provide improved adsorption properties for zeolite composites.

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Metal-organic frameworks for the adsorptive removal of pharmaceutically active compounds (PhACs): Comparison to activated carbon

Prasetya

Wenten

Franzreb

et al. 2023

Coordination Chemistry Reviews

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Single- and multi-component adsorption of selected contaminants of emerging concern from water and some of their metabolites onto hierarchical porous copper(II)-zeolite -activated carbon composite

Cited by 11 publications

References 68 publications

Progress in the design of nanoporous adsorbent materials containing transition metals for the removal of contaminants of emerging concern

Progress in the design of nanoporous adsorbent materials containing transition metals for the removal of contaminants of emerging concern

Tailoring hydrophobicity vs. water capacity of adsorbents for adsorption applications: role of composites

Metal-organic frameworks for the adsorptive removal of pharmaceutically active compounds (PhACs): Comparison to activated carbon

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