vertical velocity, new formulae for entrainment and detrainment rates can be expressed in terms of buoyancy, vertical velocity and cloud fraction. For a variety of shallow convection cases, results from large-eddy simulations show a good correspondence of these new formulae with more traditional methods to diagnose entrainment and detrainment rates. Moreover, the formulae give insight into the behaviour and the physical nature of the mixing coefficients. They explain the observed large variability of the detrainment. The formulae cannot be directly applied as a parametrization. However, it is demonstrated how they can be used to evaluate existing parametrization approaches and as a sound physical base for future parametrization developments.