Silver Acetate–Triphenylphosphine Complexes. Acetatobis(triphenylphosphine)silver(I) and its Sesquihydrate, and Bis[acetato(triphenylphosphine)silver(I)] Hydrate and its Hemihydrate

(2,2′-Bipyridyl-κ2N,N′)nitrato(triphenylphosphine-κP)silver(I)

“…The coordination geometry around silver in (I) could be described as grossly distorted tetrahedral (average bond angle = 106.5 ) or possibly as irregular. Similar distorted silver coordination environments have been observed in related complexes (Ng & Othman, 1997;Zhang et al, 2003). The crystal packing of (I) is shown in Fig.…”

Synthesis, Characterization, and Structure of a Silver(I) Compound With Thymine

“…Quality diffraction crystals of 1 was unexpectedly obtained from recrystallization of complex 2 in MeOH/diethyl ether, its structural data is consistent with the values reported by Ng and Othman in 1997. [14] Unfortunately, their report does not include the spectral properties. In the IR spectrum, the characteristic band at 1650 cm −1 is assigned to ν(C O) group of acetate ligands.…”

“…[14] PPh 3 (0.9428 g, 3.595 mmol) and AgAc (0.3000 g, 1.797 mmol) in 2:1 molar equivalents were added in mixed solvents of C 2 H 5 OH -H 2 O (30 mL:30 mL), the solution with shielding from light was warmed at 70 • C for 5 h gave a transparent liquid. After cooling, evaporation of the solution and washed with diethyl ether to give the colorless residual solids.…”

Poly[(μ3-4-aminobenzenesulfonato-κ3N:O:O)(triphenylphosphine-κP)silver(I)]

“…For the synthesis of the silver reactant used in the synthesis, see: Hanna & Ng (1999); Ng & Othman (1997). For the crystal structure of 4-aminobenzenesulfonic acid, see: Banu & Golzar Hossain (2006); Low & Glidewell (2002); Rae & Maslen (1962).…”