This paper is devoted to a comparison study of the breakdown voltage of CO 2 , N 2 , and SF 6 gases, and CO 2 -SF 6 and N 2 -SF 6 mixtures under different voltage waveforms, namely AC, DC, and lightning impulse voltages, in point-plane and sphere-sphere electrode arrangements. The influence of pressure, voltage polarity, and percentage of SF 6 in CO 2 and N 2 were studied, and equivalencies between the breakdown voltage of SF 6 and those of the considered mixtures were analyzed. It is shown that the breakdown voltage of SF 6 is the highest, whatever the applied voltage waveforms. Similarly, for a given voltage waveform, the breakdown voltage of SF 6 is the highest. The AC breakdown voltage is the lowest for all gases. The addition of small amounts of SF 6 to CO 2 and N 2 significantly improved the breakdown voltages of both natural gases. For a given breakdown voltage, the ratio between the pressure of CO 2 to that of SF 6 was generally lower than the pressure of N 2 to SF 6 , whatever the voltage waveforms.