Thermoelectric devi ces enable direct, solid state conversion of heat to electricity and vice versa. Rather than designing the shape of thermo electric units or l eg s to maximize this energy conversion, the cuboid shape of these l eg s has instead remained unchanged in large part because of limitations in the standard manufacturing process. However, the advent of additive manufacturing (a technique in which freeform geometries are built up l aye r by l aye r) offers the potential to create unique thermoelectric leg geometries desi gn ed to optimize device performance. This work explores this new realm of nove! leg geometry by simulating the thermal and electrical performance of various leg geometries such as prismatic, hollow, and layered structures. The simulations are performed for two materials, a standard bismuth telluride material found in current commercial modules and a higher manganese silicide material proposed for low cost energy conversion in high temperature applications. The results indude the temperature gradient and electrical potential developed across individual thermoelectric legs as well as thermoelectric modules with 16 legs. Even simple hollow and layered l eg geometries result in larger temperature gradients and higher output powers than the traditional cuboid structure. The clear dependence of thermal resistance and power output on leg geometry provides compelling motivation to explore additive manufacturing of thermoelectric devices.