Separator with Nitrogen–Phosphorus Flame‐Retardant for LiNi_xCo_yMn_1−x−yO₂ Cathode‐Based Lithium‐Ion Batteries

Abstract

With the pursuit of high‐energy‐density for lithium‐ion batteries (LIBs), the hidden safety problems of batteries have gradually emerged. LiNixCoyMn1−x−yO2 (NCM) is considered as an ideal cathode material to meet the urgent needs of high‐energy‐density batteries. However, the oxygen precipitation reaction of NCM cathode at high temperature brings serious safety concerns. In order to promote high‐safety lithium‐ion batteries, herein, a new type of flame‐retardant separator is prepared using flame‐retardant (melamine pyrophosphate, MPP) and thermal stable Poly(vinylidene fluoride‐co‐hexafluoropropylene) (PVDF‐HFP). MPP takes the advantage of nitrogen–phosphorus synergistic effect upon the increased internal temperature of LIBs, including the dilution effect of noncombustible gas and the rapidly suppression of undesirable thermal runaway. The developed flame‐retardant separators show negligible shrinkage over 200 °C and it takes only 0.54 s to extinguish the flame in the ignition test, which are much superior to commercial polyolefin separators. Moreover, pouch cells are assembled to demonstrate the application potential of PVDF‐HFP/MPP separators and further verify the safety performance. It is anticipated that the separator with nitrogen–phosphorus flame‐retardant can be extensively applied to various high‐energy‐density devices owing to simplicity and cost‐effectiveness.

Influence of the PET–PTFE Separator Pore Structure on the Performance of Lithium Metal Batteries

“…Polyolefin separators, such as polypropylene (PP) and PE, have been widely utilized in commercial lithium-ion batteries. − However, their application in lithium metal batteries is limited due to their inability to effectively suppress the growth of lithium dendrites, especially in batteries with a high cathode loading. Commercial PET nonwoven stands out as an ideal substrate for composite materials owing to its excellent thermal stability and inherent three-dimensional porous structure with high porosity. , Nevertheless, the large pore size limits its direct application as a separator.…”