During deep-frying, fats and oils are continuously or repeatedly subjected to high temperature in the presence of atmospheric oxygen and moisture. As a result, hundreds of chemical reactions take place in the frying oil, producing a number of harmful compounds, and are resulting in drastic changes in the quality of the oils and fried foods [1]. The most common methods to stabilize and increase the shelf life of frying oils are blending of polyunsaturated oils with more saturated or monounsaturated compounds [2,3], filtering of the oil [4,5], adding of antioxidants [6,7], and proper cleaning of fryer equipment [8,9]. Tocopherols and synthetic antioxidants such as butylated hydroxytoluene (BHT), butylated hydroanisol (BHA), and tertiary butylhydroxychinone (TBHQ) retard oxidation at ambient temperature, but they disappear from the frying medium by volatilization and steam distillation due to the high temperature and the large amounts of water boiled out of the fried food [10].The composition of unsaponifiable matter of vegetable oils including tocopherols, sterols, and hydrocarbons is of great importance for oil characteristic and stability. The addition of the unsaponifiable matter isolated from wheat germ, corn, or olive oils was found to retard oxidation in vegetable oils and model system lipids at elevated temperatures [11,12]. Gordon and Magos [13] studied the effect of sterols on the oxidation of a model system consisting of a triglyceride mixture similar in composition to olive oil at 180 °C. ∆-Avenasterol and fucosterol were effective as antioxidants whilst other sterols including sitosterol and stigmasterol were ineffective. They concluded that sterol and methyl sterols containing the ethylidene group in the side chain are responsible for the oxidative effect. The hydrocarbons of the unsaponifiable fraction of olive oil have been studied by many scientists [14,15]. Squalene is the most abundant hydrocarbon in virgin olive oil. Its concentration can be in the range of 100 to 12,000 mg/kg oil and can make more than 90% of the hydrocarbon fraction and up to 75% of the unsaponifiable fraction [16] The antioxidative effect of unsaponifiable matter from olive oil deodorizer distillate on the stability of sunflower oil during frying and on the quality of potato chips were studied. Physical and chemical characteristics of sunflower oil samples with or without different concentrations of unsaponifiable matter were examined during frying at 180 °C for ten consecutive days. The addition of 1% of unsaponifiable matter to sunflower oil showed the highest effect in retarding the oxidation deterioration of oil during frying of potato chips. This protective effect was attributed to high levels of squalene, ∆-avenasterol, and tocopherols. During ten frying days, the amount of squalene decreased to 79% and both tocopherols and ∆-avenasterol to 69% in frying sunflower oil. Oil absorbed by potato chips and the characteristics of the oil extracted from potato chips before and after three months of storage were determined. The ...