“…Three‐dimensional chemical transport models with a focus on the middle atmosphere were developed over the last decade [e.g., Rose and Brasseur , 1989; Chipperfield et al , 1993; Rasch et al , 1994; Lefèvre et al , 1994; Brasseur et al , 1997; Douglass et al , 1997; Rotman et al , 2001; Mahowald et al , 2002; Marsh et al , 2003; Rotman et al , 2004; Considine , 2004; Douglass et al , 2004]. These chemical transport models have included gas‐phase and heterogeneous reactions that represent realistically the distribution of radicals contained in the O x , HO x , NO x , ClO x , and BrO x family of constituents that are important for the O 3 balance in this region.…”