Zinc sulfide nanoparticles were fabricated by solvent evaporation method with and without using capping agent, Hexa decyltrimethyl ammonium bromide (CTAB) at room temperature. The product was received in powder form. The structure and composition of the resultant product was characterized by means of UV and FTIR spectrophotometric studies. FTIR analysis showed peaks at 352.02 cm-1 and 611.46 cm-1 for Zinc Sulfide with CTAB, corresponding to Zinc and Sulfide stretching. For Zinc Sulfide without CTAB, the same stretching frequencies were observed at 315.10 cm-1 and 615.32 cm-1. UV spectrophotometer study determined the band gap of nanocrystalline Zinc Sulfide (with and without CTAB) as 5.48 eV and 5.99 eV, respectively. The optical absorption edge exhibited a blue shift with respect to that of the bulk sample. The blue shift with the decrease in crystalline size was attributed to the quantum size effects. When ZnS was prepared without CTAB, there was decrease in the size of the nanoparticle than when it was prepared with CTAB. Even though no capping agent (CTAB) was used in preparing ZnS, the particle size was well reduced. It was achieved by stirring the solutions during preparation. No agglomeration of nanoparticles was detected