Abstract:The rate of isotopic exchange of equimolar mixtures of 3202 + 3602 dilute in Ne-1% Ar was studied over the temperature range 2625-3700 K. The reacting gas was analyzed from the reflected shock zone at 20-ps intervals with a time-of-flight mass spectrometer. Each experimental product profile obtained was compared to the corresponding computer-simulated profile calculated from an atomic mechanism by using previously published rate constants. It was observed that the growth of the exchange product exceeded that p… Show more
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