Selective Recognition and Detoxification of Deltamethrin Using Molecularly Imprinted Polymer (MIP) Matrices

Singh, Krishna Pal; Kumar, Ashok; Singh, Prashant Kumar; Sanjesh,; Singh, Rakesh; Pant, H. V.

doi:10.1080/22297928.2013.797632

Cited by 6 publications

(1 citation statement)

References 30 publications

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“…For the second-order kinetics model, the correlation coefficient, R 2 , is 0.998, whereas the first-order kinetics model has a correlation coefficient of 0.850, indicating that the adsorption kinetics of the reaction strictly follows the proposed models (see Table 2). Here, the pseudosecond-order kinetics model assumes that adsorption of DNOC by MIP occurs in two stages: when the adsorbate interacts with the surface of the adsorbent and when the adsorbate interacts with the adsorbate (Singh et al, 2014). According to the Langmuir adsorption model, adsorption of a printed molecule only occurs on a monolayer surface, and the rate of adsorption does not depend on the number of molecules adsorbed (Abouelella et al, 2018).…”

Section: Adsorption Test Resultsmentioning

confidence: 99%

Molecularly Imprinted Polymer Solid-Phase Extraction (MISPE) for the Determination of Dinitro-ortho-cresol (DNOC) and Its Risk Assessment in Tomatoes

Rosmalina¹,

Amran

Ramadan

et al. 2023

molekul

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In this study, the molecularly imprinted polymer solid-phase extraction (MISPE) method for the determination of dinitro-ortho-cresol (DNOC) before HPLC (High-performance liquid chromatography) analysis was conducted. This study aims to analyze the sorption behavior and the potential use of molecularly imprinted polymers (MIP) for DNOC extraction. MIP was prepared using a combination of methacrylic acid as the functional monomer; ethylene glycol dimethacrylate as the crosslinker, benzoyl peroxide as the initiator, and acetonitrile as the porogen. The results showed that the optimum adsorption of the material was achieved at pH 5 for a contact time of 30 min with an adsorption capacity of 137 mg/g. The ideal eluent for desorption was a mixture of methanol and acetic acid with a ratio of 3:1. The calculations showed that the adsorption process followed the Sips adsorption isotherm model (n = 0.967), which indicated adsorption on both homogeneous and monolayer surfaces. Reusability studies that were conducted via three consecutive adsorption-desorption cycles resulted in recovery values of 109.4%, 108.8%, and 101.1%. The concentration of DNOC obtained from tomato samples was 0.65 mg/kg with a recovery rate of 87.17%; this was within the tolerable range between 80% and 110%. Based on the high recovery and low LoQ, this method can be used to quantify DNOC quickly.

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Section: Adsorption Test Resultsmentioning

confidence: 99%