Abstract::
Formic acid (HCOOH) as an inexpensive and versatile reagent has attracted broad attention in the field of green synthesis and chemical industry. Formic acid acts not only as a convenient and less toxic CO surrogate, but also as an excel-lent formylative reagent, C1 source and hydrogen donor in organic reactions. Over the past decades, many exciting contribu-tions have been made which have helped chemists to understand the mechanisms of these reactions. The review will exam-ine recent advances in the utilization of formic acid as economical, practical and multipurpose reactant in synthetic trans-formations.