Selective Oxido‐Reductive Processes by Nucleophilic Radical Addition under Mild Conditions

Free-Radical Addition to Ketimines Generated In Situ. New One-Pot Synthesis of Quaternary α-Aminoamides Promoted by a H2O2/TiCl4−Zn/HCONH2 System

“…The use of free radical reactions in organic synthesis has continued to increase in the past years, providing multiple advantages over classical ionic chemistry, which often requires expensive reagents and hazardous operating conditions . In particular, nucleophilic radical addition to the carbon atom of imine derivatives has attracted much attention in the past decade as a versatile route to the synthesis of a wide range of polyfunctional molecules, and many procedures based on this convenient approach have been developed.…”