The process optimization of the Si 0.7 Ge 0.3 Fin formation for the shallow trench isolation first strategy is systematically demonstrated in this paper. The optimized Si Fin etching and recess process are firstly developed to attain an improvement of side wall roughness and profile for the Si 0.7 Ge 0.3 selective epitaxial growth. Moreover, a new developed photoresist etching back process, inserted between Tetramethylammonium hydroxide etching and Si 0.7 Ge 0.3 selective epitaxial growth, is employed to eliminate the surface defects completely. Furthermore, an optimized pre-baking temperature of Si 0.7 Ge 0.3 selective epitaxial growth results in a more rounding V-shaped Si recess profile compared with its V-shaped profile produced by the Tetramethylammonium hydroxide etching. The incoming profile optimization is critical to achieve the structural defects free for the Si 0.7 Ge 0.3 layer selective epitaxial growth. Finally, a high crystalline quality of the Si 0.7 Ge 0.3 Fin formation inside narrow trench is realized by utilizing the SiGe chemical mechanical polishing and Shallow Trench Isolation recess process. This work presents a good technique for high-mobility pMOSFETs in future technology node.