At passive non-volcanic rifted continental margins, the interrelation between rifting, un-roofing of continental mantle in a broad continent-ocean transition zone (COT), and the onset of seafloor spreading is even after decades of geological and geophysical investigations still poorly understood (e.g., Sun et al., 2018). Deep drilling at two non-volcanic margins revealed that at the Iberia-Newfoundland margin the COT is characterized by a wide domain of exhumed mantle (Dean et al., 2000;Whitmarsh et al., 2001), while the mid-northern South China Sea (SCS) margin shows fast break-up without mantle exhumation (Larsen et al., 2018). However, without deep drilling and hence sampling the type of basement rocks, constraints from geophysical imaging alone, are usually too tenuous to uniquely outline the detailed crustal structure forming the seafloor. In seismic exploration, multi-channel seismic data (MCS) provide exquisite basement geometry and shallow crustal characteristics (e.g., Dean et al., 2015;Minshull et al., 2014), while the P wave velocity structure derived from seismic refraction and wide-angle data helps to define the crustal nature (e.g., Dean et al., 2000). However, these traditional approaches are inadequate to reveal the enigmatic structure and composition of the COT. For example, serpentinization of exhumed mantle can hardly be unscrambled from crustal rocks since the P wave velocity overlap at ∼6.5-7.2 km/s of gabbro and partially serpentinized peridotite (Christensen, 2004;Grevemeyer, Hayman, et al., 2018). Further, reflection energy