Seed assisted synthesis of an anionic metal–organic framework membrane for selective and permeable hydrogen separation

Abstract

Hydrogen selective metal organic framework (MOF) membranes with excellent performances are still in high demand. Here, we are developing an anionic MOF material of CPM-5 into a membrane for H2...

Graphene Nanoribbon Hybridization of Zeolitic Imidazolate Framework Membranes for Intrinsic Molecular Separation

“…The H 2 /CO 2 separation performance was compared with that of previous membrane materials, including MOFs, zeolites, and two‐dimensional (2D) materials (Figure 3e and Table S2) [33–70] . Ideal separation performance (marked with a black star) of the ZIF‐8/GNR/alumina(300) membrane surpasses the upper bounds of reported polycrystalline MOF membrane performance and is located in the state art range of 2D materials‐based membranes (e.g.…”

Immobilization of ferrocene and its derivatives within metal–organic frameworks with high loadings toward efficient oxygen evolution reaction

“…1 Hydrogen (H 2 ) has been deemed as an ideal energy carrier owing to its high massenergy density and carbon-free emission during combustion. [2][3][4] Electrochemical water splitting is an efficient approach for massive production of high purity H 2 at low cost, and thus has sparked increasing attention. Nevertheless, the oxygen evolution reaction (OER) at the anode possesses sluggish kinetics due to its four-electron transfer process, which limits the development of electrochemical water splitting.…”

Three-Dimensional PdPbBi Nanoalloy-Embedded Reduced Graphene Oxide/CPM-5 Prismatic Composite as High-Efficiency Electrocatalysts for Ethylene Glycol Oxidation

“…Also, MOFs have the advantages of uniform shape and size, porous, diverse, and tunable surfaces . For instance, CPM-5 (crystalline porous materials) has been used as a sulfur fixative for Li–S batteries, zinc–air batteries, and as an H 2 separation membrane. − However, MOFs have poor electrical conductivity and low mass permeability . At present, most researchers choose carbon as the support material of the catalyst, such as carbon nanotubes, carbon nanofibers, carbon black, and so on. , Reduced graphene oxide (rGO) has the advantages of good stability, corrosion resistance, conductivity, and a large surface area, which can promote electron transmission, increase the contact area of reactants, and thus improve catalytic efficiency .…”