To account for the published yield curves, f (E 0 ), of some insulators such as diamond, an elementary theory of secondary electron emission (s.e.e) is used. This theory permits the estimation of the effective attenuation lengths of the emitted electrons during their transport and to explain the signi®-cant differences between the s.e.e. from metals and that from insulators. Some practical consequences related for instance to the lack of topographic contrast in LVSEM and to charging mechanisms in electron beam techniques are then deduced.The secondary electron emission yield is an important parameter of electron/solid interactions. In contrast to the metal case, its maximum value for insulators is far larger than the unity but it is a function of the crystalline state of the specimen, of its bias and of the irradiation conditions. Based on the use of a very simple semi-empirical equation, this paper is an attempt to account for the role of the various parameters involved in the s.e.e. yield of insulators. Practical consequences on the contrast of images in SEM and on charging mechanisms in e À irradiated insulators are also deduced. The One-Dimensional Constant-Loss Theory of s.e.e. This elementary theory, developed by Salow [1], Bruining [2] Dione [3] and many others [4 ± 6], is based on the fact that the average number of secondaries, n(z, E 0 ), produced per incident primary in a layer of thickness dz at the depth z below the surface is given by:where E(e.h) is the energy required to excite one secondary electron inside the solid (electron/hole pair generation) and R is the range of the incident electron of primary energy E 0 . The last identity in Eq. (1) is the result of approximating the stopping power to the ratio of the incident electron energy E 0 and the electron range. Assuming a one dimensional exponential attenuation for the transport of the secondaries towards the surface, f a 1/2 exp Àz/!, the equation obtained for , is:where B is the escape probability (into the vacuum); ! is an effective attenuation length and the geometrical factor 1/2, represents the fraction of the generated secondaries moving towards the surface. Next, the range could be approximated by a power law of the form:R C E n 0 3 with n 1.35 (for the energy range of interest, here) and with the material constant C given by 2.6Á10 2 (A/&Z ) where R is in mm E 0 in keV and & in g/cm 3 , A and Z are the mean atomic mass and atomic number respect [3 ± 5]. Finally, it is easy to compare the experimental results obtained from the use of short pulse excitations (to prevent charging effects) and the above simple Mikrochim. Acta 132, 173±177 (2000)