SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC

Israr, Farrukh; Kim, Duk Kyung; Kim, Yeongmin; Chun, Wongee

doi:10.5935/0100-4042.20160068

Cited by 13 publications

(12 citation statements)

References 34 publications

(41 reference statements)

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“…337-450 • C) (mass change of 54-57 %, Figure S1, SI) [56,60]. The TGA curves are in agreement with reported curves for NiCo-BTC and Ni-BTC [35,43,60,61].…”

Section: Synthesis and Characterization Of The Ni-btc Analogssupporting

confidence: 86%

“…Thermogravimetric analyses (TGA) under N 2 atmosphere yield a similar curvature for all Ni-BTC analogs (Figure S1, SI). In the range of 30-320 • C the initial weight losses until decomposition can be attributed to the loss of crystal solvent molecules (DMF, H 2 O) incorporated in the cavities [61]. After complete solvent loss the BTC-linker together with the MOF structure decomposes around 350-600 • C (Lit.…”

Section: Synthesis and Characterization Of The Ni-btc Analogsmentioning

confidence: 99%

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Nickel-Based Metal-Organic Frameworks as Electrocatalysts for the Oxygen Evolution Reaction (OER)

et al. 2022

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The exploration of earth-abundant electrocatalysts with high performance for the oxygen evolution reaction (OER) is eminently desirable and remains a significant challenge. The composite of the metal-organic framework (MOF) Ni10Co-BTC (BTC = 1,3,5-benzenetricarboxylate) and the highly conductive carbon material ketjenblack (KB) could be easily obtained from the MOF synthesis in the presence of KB in a one-step solvothermal reaction. The composite and the pristine MOF perform better than commercially available Ni/NiO nanoparticles under the same conditions for the OER. Activation of the nickel-cobalt clusters from the MOF can be seen under the applied anodic potential, which steadily boosts the OER performance. Ni10Co-BTC and Ni10Co-BTC/KB are used as sacrificial agents and undergo structural changes during electrochemical measurements, the stabilized materials show good OER performances.

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“…337-450 • C) (mass change of 54-57 %, Figure S1, SI) [56,60]. The TGA curves are in agreement with reported curves for NiCo-BTC and Ni-BTC [35,43,60,61].…”

Section: Synthesis and Characterization Of The Ni-btc Analogssupporting

confidence: 86%

Section: Synthesis and Characterization Of The Ni-btc Analogsmentioning

confidence: 99%

Nickel-Based Metal-Organic Frameworks as Electrocatalysts for the Oxygen Evolution Reaction (OER)

et al. 2022

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“…The lower window of the detector electronics was increased using Si-Einkristalle at the default value of 0.11–0.19 V to minimize the effects of fluorescence. The Rietveld refinement technique [ 83 , 84 , 85 ] with software suite Diffrac TOPAS 4.2 [ 33 , 86 , 87 , 88 ] was used to determine the L1 structure. The single-crystal structure of L1 , used to compare our results, has been previously reported [ 34 ].…”

Section: Methodsmentioning

confidence: 99%

Structural Characterization, DFT Calculation, NCI, Scan-Rate Analysis and Antifungal Activity against Botrytis cinerea of (E)-2-{[(2-Aminopyridin-2-yl)imino]-methyl}-4,6-di-tert-butylphenol (Pyridine Schiff Base)

et al. 2020

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Botrytis cinerea is a ubiquitous necrotrophic filamentous fungal phytopathogen that lacks host specificity and can affect more than 1000 different plant species. In this work, we explored L1 [(E)-2-{[(2-aminopyridin-2-yl)imino]-methyl}-4,6-di-tert-butylphenol], a pyridine Schiff base harboring an intramolecular bond (IHB), regarding their antifungal activity against Botrytis cinerea. Moreover, we present a full characterization of the L1 by NMR and powder diffraction, as well as UV–vis, in the presence of previously untested different organic solvents. Complementary time-dependent density functional theory (TD-DFT) calculations were performed, and the noncovalent interaction (NCI) index was determined. Moreover, we obtained a scan-rate study on cyclic voltammetry of L1. Finally, we tested the antifungal activity of L1 against two strains of Botrytis cinerea (B05.10, a standard laboratory strain; and A1, a wild type strains isolated from Chilean blueberries). We found that L1 acts as an efficient antifungal agent against Botrytis cinerea at 26 °C, even better than the commercial antifungal agent fenhexamid. Although the antifungal activity was also observed at 4 °C, the effect was less pronounced. These results show the high versatility of this kind of pyridine Schiff bases in biological applications.

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“…These peaks can be indexed to (002), (112), (022), (013), (222), (114), (233), (224), (134), (044), (334), (244) and (235) crystal structure of ZIF based materials which is almost in agreement with the previously reported NiCo-based MOFs. 30,[43][44][45][46][47] XPS test was conducted to analyze the surface chemical states and bonding of the samples. Fig.…”

Section: Structural Characterization Methodsmentioning

confidence: 99%

A 2D metal–organic framework/reduced graphene oxide heterostructure for supercapacitor application

Beka

et al. 2019

RSC Adv.

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SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC

Cited by 13 publications

References 34 publications

Nickel-Based Metal-Organic Frameworks as Electrocatalysts for the Oxygen Evolution Reaction (OER)

Nickel-Based Metal-Organic Frameworks as Electrocatalysts for the Oxygen Evolution Reaction (OER)

Structural Characterization, DFT Calculation, NCI, Scan-Rate Analysis and Antifungal Activity against Botrytis cinerea of (E)-2-{[(2-Aminopyridin-2-yl)imino]-methyl}-4,6-di-tert-butylphenol (Pyridine Schiff Base)

A 2D metal–organic framework/reduced graphene oxide heterostructure for supercapacitor application

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