This paper deals with the motivation of students as one of the problems in the implementation of Distance learning method. Also attention will be paid on the questions of students' ability to organize time for learning as well as possession of appropriate personal life habits, as each of the important factors of a successful student's motivation for the use of Distance learning method. The research in this paper includes both empirical and theoretic character, conducted with questionnaire survey on a representative sample. It should provide answers about the impact and importance of user motivation during class organized with Distance learning method, in relation to teaching realized in the traditional way.