Abstract[K+(2,2,2‐crypt)]2Ge92– containing the deltahedral Zintl anion Ge92– has been isolated from a solution of K4Ge9 in ethylenediamine in the presence of 2,2,2‐crypt, intended as an intermediate in mixed‐cluster synthesis. The subsequent crystallographic characterisation shows the closo‐Ge92– cluster unit to be tricapped trigonal‐prismatic with a symmetry very close to D3h. Each Ge92– unit is surrounded by two 2,2,2‐crypt units, each with a chelated K+ cation, viz. [K+(2,2,2‐crypt)]. The structure characterisation of this ordered Ge92– cluster is surprisingly enough the first one reported. A chemical bonding analysis reveals two local minima of D3h symmetry, with that of lowest energy being highly similar to that resulting from the crystallographic analysis of low‐temperature data. The cluster interaction scheme is based on highly delocalised bonding.