Sättigungsdrucke einiger Senföle und Sulfide

Bauer, Hugo; Burschkies, Karl

doi:10.1002/cber.19350680645

Cited by 11 publications

(3 citation statements)

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“…Vapor pressure data for thiodiglycol. ◊, this work; ▲, ref ; +, ref ; ○, ref ; ☆, ref ;⊗, ref ; *, ref ; ⧫, ref ; ●, ref ; □, manufacturers’ data sheets. The lower value found in ref , equivalent to P = (6.6) Pa, appears to be in error.…”

Section: Discussionmentioning

confidence: 99%

“…The earliest primary source reference containing experimental vapor pressure data and a detailed discussion of the method used was published by Bauer and Burschkies in 1935; that article contains 15 data points at T = (283.15 to 353.15) K and P = (93 to 400) Pa. Several subsequent reports of the normal and reduced pressure boiling points of TDG can be found in the literature. − All of the subsequent data conflict with the data of Bauer and Burschkies; however, none of them cites or discusses the earlier data. The lower value provided by Bronnert and Saunders and Szabo and Stiller’s value at P = (4533) Pa conflicts with all of the data in the literature, and the reasons for those differences are unclear.…”

Section: Introductionmentioning

confidence: 99%

“…Literature vapor pressure data and Antoine equation for thiodiglycol. – – −, ref Antoine equation; ▲, ref ; △, compilations; □, manufacturers’ data sheets; +, ref ; ○, ref ; ☆ ref ; ⊗ ref ; *, ref ; ⧫, ref ; ●, ref . The lower value found in ref , equivalent to P = (6.6) Pa, appears to be in error.…”

Section: Introductionmentioning

confidence: 99%

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Vapor Pressure of Thiodiglycol

2014

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Thiodiglycol (TDG), also known as bis(2-hydroxyethyl) sulfide and thiodiethanol, is a precursor of the blister agent sulfur mustard (bis(2-chloroethyl) sulfide). It is also a hydrolytic degradation product, and as such, it is of considerable forensic interest to the chemical defense community. Experimental vapor pressure data have been reported previously for TDG at T = (283.15 to 353.15) K, in addition to reduced-pressure boiling points at T = (353.15 to 454.65) K. New data have been measured using two complementary American Society for Testing and Materials International methods at T = (417.75 to 538.58) K by differential scanning calorimetry and in the ambient temperature range using saturator methodology at T = (298.15 to 313.15) K. The new TDG vapor pressure data are in sharp contrast to widely accepted values from previous literature.

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Section: Discussionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Vapor Pressure of Thiodiglycol

2014

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Toxicity of Beta–phenethyl Isothiocyanate to Certain Fungi

Hooker

Walker

Smith

1943

American J of Botany

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Conversion of metham‐sodium to methyl isothiocyanate and basic data on the behaviour of methyl isothiocyanate in soil

Smelt¹,

Leistra²

1974

Pestic. Sci.

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Data were collected that are needed to simulate soil fumigation with metham‐sodium with computation models. The rate of conversion of metham‐sodium into methyl isothiocyanate was dependent on temperature and soil type, and conversion was usually completed within a few hours. In comparison with dichloropropene, there was a higher water/gas distribution ratio and thus a slower vapour diffusion. Adsorption from the water phase onto the solid phase was weaker. The first‐order rate equation described the decomposition of methyl isothiocyanate and the half‐lives varied from a few days to a few weeks according to temperature and soil type.

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Sättigungsdrucke einiger Senföle und Sulfide

Cited by 11 publications

References 0 publications

Vapor Pressure of Thiodiglycol

Vapor Pressure of Thiodiglycol

Toxicity of Beta–phenethyl Isothiocyanate to Certain Fungi

Conversion of metham‐sodium to methyl isothiocyanate and basic data on the behaviour of methyl isothiocyanate in soil

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