2009
DOI: 10.1016/j.molcata.2009.01.006
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Room temperature selective oxidation of toluene over vanadium substituted polyoxometalate catalysts

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Cited by 75 publications
(16 citation statements)
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“…However, one of the major problems of homogenous catalysis is the difficult separation of the catalyst from the reaction mixture, which is often energy intensive and generates a large volume of waste 10. As a result of the easy recovery of the catalyst from products and solvent‐free reaction conditions, heterogeneous catalytic oxidation has attracted much attention in recent years 11–16. For example, single‐site solid catalyst FeAlPO‐5 was used for toluene oxidation in high yield by Raja and Thomas 17.…”
Section: Introductionmentioning
confidence: 99%
“…However, one of the major problems of homogenous catalysis is the difficult separation of the catalyst from the reaction mixture, which is often energy intensive and generates a large volume of waste 10. As a result of the easy recovery of the catalyst from products and solvent‐free reaction conditions, heterogeneous catalytic oxidation has attracted much attention in recent years 11–16. For example, single‐site solid catalyst FeAlPO‐5 was used for toluene oxidation in high yield by Raja and Thomas 17.…”
Section: Introductionmentioning
confidence: 99%
“…Zn-en Cu-uitgeruilde heteropolisuurkatalisators is bestudeer met betrekking tot verskeie reaksies, soos die Knoevenagel-kondensasiereaksie, oksidasiereaksies en suurgekataliseerde organiese transformasies (Jagadeeswaraiah et al, 2014;Patil et al, 2014;Rao et al, 2012;Pope, 1991;Viswanadham et al, 2016). Khabazzadeh et al (2009) 2014) die laetemperatuur-aktivering van metaan oor 'n Zn-uitgeruilde heteropolisuur bestudeer het wat gelei het tot die selektiewe vorming van metanol en asynsuur tydens die reaksie.…”
Section: Katalisatorkarakteriseringunclassified
“…Khabazzadeh et al (2009) 2014) die laetemperatuur-aktivering van metaan oor 'n Zn-uitgeruilde heteropolisuur bestudeer het wat gelei het tot die selektiewe vorming van metanol en asynsuur tydens die reaksie. Jagadeeswaraiah et al (2014) het aangetoon dat die toevoeging van Zn 2+ ione in die sekondêre struktuur van heteropolisure doeltreffend was tydens gliserolkarbonaatsintese uit gliserol en ureum, terwyl Rao et al (2012), wat niobia ondersteun op Zn-uitgeruilde fosfowolframsuur berei het, opgemerk het dat die katalisators goeie aktiwiteit getoon het tydens die omskakeling van furfurielalkohol na butiellevulinaat en dit in verband gebring het met die suurposisies van katalisators. In 'n studie wat gedoen is met behulp van Cu-fosfomolibdeensuur (Cu-PMA), het die outeurs bevind dat die Cu-katalisator beter katalitiese werkverrigting toon as die blanko, dit wil sê fosfomolibdeensuur (PMA).…”
Section: Katalisatorkarakteriseringunclassified
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“…They have impressive therapeutic and catalytic activity, , probably due to their multiple oxidation states . High stability of alkane/alkene aromatics imposes difficulties to their oxidation generally performed in agrochemical and pharmaceutical industries. Besides, the activation of carbon–hydrogen bond is challenging and requires hazardous conditions like high temperature, strong acidic medium, etc.…”
Section: Introductionmentioning
confidence: 99%