Hybrid materials have been formed using an epoxy polymeric matrix and a range of inorganic particles, including mica and organically-modified montmorillonites ('organoclays'), with various concentrations of the silicate modifier up to about 30wt.% depending upon the viscosity increase induced by the presence of the silicate. Wide-angle and small-angle X-ray scattering plus transmission electron microscopy were used to identify the morphologies produced, which included particulate, intercalated and ordered exfoliated. The modulus of these composites increased with the weight fraction of silicate.