Pyrolysis is a viable technique to convert waste tires into recyclable products, as the dumping of these scrap tires pose a serious environmental threat. In the present investigation, a detail methodology to fabricate and characterize the carbonaceous filler (in the form of nanocarbon black obtained from pyrolysis of waste tires) modified epoxy resin composites has been retrieved. The composites with varying carbon filler content (0, 5, 10, and 15 wt%) were fabricated using the manual hand lay‐up and compression molding techniques. The morphological analysis (field‐emission scanning electron microscopy test) revealed that the synthesized pyrolytic carbon black was in nanoscale and uniformly dispersed in the epoxy matrix. Various physical (density and water absorption), mechanical (tensile, compression, flexural, hardness, and impact), electrical and thermal (differential thermal analysis and thermogravimetric analysis) tests were done to completely examine the nanocomposite developed. We found that the 5 wt% of carbon black in epoxy resin exhibited the best mechanical properties and was complemented by the microstructural (scanning electron microscopy and X‐ray diffraction) tests analysis. High tensile strength and hardness than neat epoxy resin makes this composite a potential candidate for polymer coatings in automotive industries.
A novel hybrid composite was developed from natural fibers and the mechanical properties were investigated in this work. The palm sheath and sugarcane bagasse fibres were the natural fibers used and epoxy resin was the matrix. By using compression‐molding machine, various samples were prepared by varying the weight proportions of fibers. The performance of fibers was investigated under untreated and NaOH treated conditions. The tensile properties, flexural properties, hardness, and impact properties were evaluated using ASTM standards. The best sample was determined based on the experimental results. The best sample had the tensile strength of 19.80 ± 0.78 MPa, Young's Modulus of 0.953 ± 0.076 GPa, flexural strength of 28.79 MPa, impact strength of 2 kJ/m2, and the hardness value of 38.02 HD. The best sample was used to develop an automobile dashboard to justify its application.
In this research article, the mechanical analysis and microstructure investigation of chicken feather fiber with carbon residuum (CR) (obtained from crumb rubber) fused with epoxy resin hybrid composite has been done. The fibers surface was alkali treated with caustic soda (sodium hydroxide) to improve the interfacial bonding with matrix and reinforcement. Herein, the composites were fabricated using the hand lay‐up technique. Chicken feathers in form of reinforcing fibers were taken in various weight percentages of 1, 3, 5, and 7. Various mechanical tests were performed in accordance with the ASTM standards, and it was perceived that the 5 weight percentage of chicken feathers recorded the optimum impact test results. Finally, the hybrid composites were fabricated with this weight percentage of feathers and varying weight percentages (0.5, 1, 1.5, 2, and 2.5) of CR. Mechanical testing was then conducted on these hybrid composites and determined that the tensile strength, flexural strength and impact strength showed a substantial enhancement. The justification of this enhancement was provided through the microstructural tests that includes the scanning electron microscopy and X‐ray diffraction analysis. Best results were forecasted for 5 wt% chicken feather and 1 wt% of CR hybrid composites amongst various combinations tried. Thus, noteworthy improvement in case of hybrid composite was seen as compared with neat epoxy. POLYM. COMPOS., 40:2690–2699, 2019. © 2018 Society of Plastics Engineers
Over past few decades, the electronic boards density and performance are enhanced by entrenching the components in the interior surfaces of the printed circuit boards (PCBs).The worthiness of this novel innovation has to be probed to warranty the functioning of electronic boards acquiesced to callous environments. In this study, a novel advancement concentrating on the development of bio-based materials for the PCB applications has been documented. The biobased composite from rice husk-epoxy resin could impendingly substitute the conventional synthetic fiber reinforced epoxy composites in PCB applications. The essential properties of biocomposites were assessed such as tensile and bending properties, dielectric property, thermal properties, moisture absorption, microdrilling, biodegradability, and flammability. Results obtained found that, these biocomposites were promising for PCB application.
In this experimental investigation, the authors have fabricated and characterized composites made from pyrolysis oil rubber and epoxy resin. As the dumping of waste scrap tires poses a serious environmental threat, the pyrolysis oil rubber was extracted from these waste tires only. The prepared blend having pyrolysis oil with various weight percentages (wt%) was examined on the basis of various physical, microstructural, mechanical, and thermal tests. The microstructural tests (scanning electron microscopy and X-ray diffraction) analysis complemented with the mechanical tests (tensile, compression, flexural, hardness, and impact) results and confirmed that the 4.4 wt% of pyrolysis oil in epoxy resin sample exhibited the best results in toughening of the polymer network. Furthermore, the thermal analysis (differential thermal analysis and thermogravimetric analysis), electrical conductivity, density, water absorption, gas chromatography-mass spectroscopy, and Fourier-transform infrared tests for the composites were also performed. Low density and high tensile strength than neat epoxy resin makes this composite a potential candidate for fabricating lightweight structures and in polymer coatings for automotive industries.
Owing to their biodegradable nature and cost-effectiveness, natural fibers have attracted the attention of various material scientists. One such fiber is human hair (HH), which is viscoelastic-plastic in nature and encloses well-characterized microstructures within it. An important aspect is that a strand of HH having a diameter of 60 μm is capable of withstanding a force of 100–150 grams/fiber. However, wastage of HH on an enormous scale poses an environmental challenge. Therefore, the authors have utilized this novel fiber in the field of composites and revealed the systematic methodology of fabricating HH with polymers using the wet hand lay-up technique. The diverse compositions of polymer-HH composite, with varying HH weight percentages (wt.%) of 5, 6, 7, 8, 9, and 10 %, were put to investigation. In the present work, treatment of HH with potassium hydroxide and curing of polymer further enhanced the bonding properties of composites. The specimens were examined micro-structurally through scanning electron microscopy (SEM) and X-ray powder diffraction (XRD) tests, followed by the mechanical tests: tensile, compression, flexural, hardness, and impact. Both the microstructural and mechanical tests complemented each other and confirmed that the cured polymer composite speckled with 7 wt.% of HH fiber content was the best of all formulations, as it provided the highest magnification in mechanical properties relative to neat polymer. Finally, the thermal analysis was done via thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) techniques.
Due to their exceptional properties, graphene and hexagonal boron nitride (h‐BN) nanofillers are emerging as potential candidates for reinforcing the polymer‐based nanocomposites. Graphene and h‐BN have comparable mechanical and thermal properties, whereas due to high band gap in h‐BN (~5 eV), have contrasting electrical conductivities. Atomistic modeling techniques are viable alternatives to the costly and time‐consuming experimental techniques, and are accurate enough to predict the mechanical properties, fracture toughness, and thermal conductivities of graphene and h‐BN‐based nanocomposites. Success of any atomistic model entirely depends on the type of interatomic potential used in simulations. This review article encompasses different types of interatomic potentials that can be used for the modeling of graphene, h‐BN, and corresponding nanocomposites, and further elaborates on developments and challenges associated with the classical mechanics‐based approach along with synergic effects of these nano reinforcements on host polymer matrix. This article is categorized under: Molecular and Statistical Mechanics > Molecular Mechanics Structure and Mechanism > Computational Materials Science Molecular and Statistical Mechanics > Molecular Dynamics and Monte‐Carlo Methods
Aim of this article was to investigate the effect of grain boundaries on the interfacial properties of bi-crystalline graphene/polyethylene based nanocomposites. Molecular dynamics based atomistic simulations were performed in conjunction with the reactive force field parameters to capture atomic interactions within graphene and polyethylene atoms, whereas non-bonded interactions were considered for the interfacial properties. Atoms at the higher energy state in bi-crystalline graphene helps in improving the interaction at the nanocomposite interphase. Geometrical imperfections such as wrinkles and ripples helps the bi-crystalline graphene in increasing the number of adhesion points between the nanofiller and matrix, which eventually improves the strength and toughness of nanocomposite. These outcomes will help in opening new opportunities for defective nanofillers in the development of nanocomposites for future applications.
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