“…22 Molecular selfassembly at surfaces is determined by surface chemistry, surface orientation, surface anisotropy, molecular conformational flexibility, and in some cases the nonplanarity of the molecules. 5,14,17,23 Rubrene (5,6,11,12-tetraphenyltetracene, C 42 H 28 ) was first synthesized over 80 years ago. 24 Its molecular structure was debated in the early literature, 25,26 but has now been established by X-ray crystallography.…”