We report a real-space visualization of the formation of hydrogen bonding in 8-hydroxyquinoline (8-hq) molecular assemblies on a Cu(111) substrate, using noncontact atomic force microscopy (NC-AFM). The atomically resolved molecular structures enable a precise determination of the characteristics of hydrogen bonding networks, including the bonding sites, orientations, and lengths. The observation of bond contrast was interpreted by ab initio density functional calculations, which indicated the electron density contribution from the hybridized electronic state of the hydrogen bond. Intermolecular coordination between the dehydrogenated 8-hq and Cu adatoms was also revealed by the submolecular resolution AFM characterization. The direct identification of local bonding configurations by NC-AFM would facilitate detailed investigations of intermolecular interactions in complex molecules with multiple active sites.
Two-dimensional (2D) magnets with intrinsic ferromagnetic/antiferromagnetic (FM/AFM) ordering are highly desirable for future spintronic devices. However, the direct growth of their crystals is in its infancy. Here we report a chemical vapor deposition approach to controllably grow layered tetragonal and non-layered hexagonal FeTe nanoplates with their thicknesses down to 3.6 and 2.8 nm, respectively. Moreover, transport measurements reveal these obtained FeTe nanoflakes show a thickness-dependent magnetic transition. Antiferromagnetic tetragonal FeTe with the Néel temperature ( T N ) gradually decreases from 70 to 45 K as the thickness declines from 32 to 5 nm. And ferromagnetic hexagonal FeTe is accompanied by a drop of the Curie temperature ( T C ) from 220 K (30 nm) to 170 K (4 nm). Theoretical calculations indicate that the ferromagnetic order in hexagonal FeTe is originated from its concomitant lattice distortion and Stoner instability. This study highlights its potential applications in future spintronic devices.
Topological states emerge at the boundary of solids as a consequence of the nontrivial topology of the bulk. Recently, theory predicts a topological edge state on single layer transition metal dichalcogenides with 1T’ structure. However, its existence still lacks experimental proof. Here, we report the direct observations of the topological states at the step edge of WTe2 by spectroscopic-imaging scanning tunneling microscopy. A one-dimensional electronic state residing at the step edge of WTe2 is observed, which exhibits remarkable robustness against edge imperfections. First principles calculations rigorously verify the edge state has a topological origin, and its topological nature is unaffected by the presence of the substrate. Our study supports the existence of topological edge states in 1T’-WTe2, which may envision in-depth study of its topological physics and device applications.
Two-dimensional materials with out-of-plane (OOP) ferroelectric and piezoelectric properties are highly desirable for the realization of ultrathin ferro- and piezoelectronic devices. We demonstrate unexpected OOP ferroelectricity and piezoelectricity in untwisted, commensurate, and epitaxial MoS 2 /WS 2 heterobilayers synthesized by scalable one-step chemical vapor deposition. We show d 33 piezoelectric constants of 1.95 to 2.09 picometers per volt that are larger than the natural OOP piezoelectric constant of monolayer In 2 Se 3 by a factor of ~6. We demonstrate the modulation of tunneling current by about three orders of magnitude in ferroelectric tunnel junction devices by changing the polarization state of MoS 2 /WS 2 heterobilayers. Our results are consistent with density functional theory, which shows that both symmetry breaking and interlayer sliding give rise to the unexpected properties without the need for invoking twist angles or moiré domains.
Submonolayer coverages of the molecule 3,4,9,10-perylene tetracarboxylic dianhydride (PTCDA) deposited on NaCl(001) surfaces were imaged with high resolution noncontact-atomic force microscopy. Two island types were observed: monolayer islands with a p3x3 epitaxy at low coverage and a mixture of these and bulklike crystallites at higher coverage. The transition between the pure monolayer islands and mixed islands occurs at approximately 0.85 ML, corresponding to a complete p3x3 layer. Calculations show the p3x3 epitaxy to be incompatible with a multilayer crystal of PTCDA. Consequently, the growth of additional layers results in an adaptation of the interface structure forcing a dewetting transition.
The giant anisotropic Raman response of encapsulated ultrathin black phosphorus (BP) is reported by uniaxial strain. A modified bending technique is employed to apply precise uniaxial tensile strain along the zigzag or armchair direction of the ultrathin BP encapsulated by a layer of polymethyl methacrylate. The Raman shift rates of the A 1 g, B 2g, and A 2 g modes are significantly distinct for strain applied along different directions. For the strain applied along zigzag direction, the Raman shift rate of the B 2g mode can reach a remarkable value of ≈−11 cm−1/% strain. In addition, the Grüneisen parameter is as high as ≈2.5, which is the largest among all the reported common 2D materials. Density functional perturbation theory calculations are performed to understand the exceptional anisotropic strain response discovering that not only the bond lengths but also the bond angels are changed in the strained ultrathin BP, which lead to the giant anisotropic Raman response. Furthermore, an alternative method based entirely on the strained ultrathin BP and nonpolarized Raman spectroscopy is demonstrated to determine the crystallographic orientations of ultrathin BP. This work paves a way to study the strain‐induced anisotropic electrical conductance and magnetotransport properties of BP.
We report a first principles study of spin transport under finite bias through a graphene-ferromagnet (FM) interface, where FM = Co(111), Ni(111). The use of Co and Ni electrodes achieves spin efficiencies reaching 80% and 60%, respectively. This large spin filtering results from the materials specific interaction between graphene and the FM which destroys the linear dispersion relation of the graphene bands and leads to an opening of spin-dependent energy gaps of ≈0.4-0.5 eV at the K points. The minority spin band gap resides higher in energy than the majority spin band gap located near E(F), a feature that results in large minority spin dominated currents.
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