“…This occurrence, known as the Burstein-Moss effect [38], justifies the enhanced conductivity of these samples with respect to ZnO reported in literature [39] and explains the hereby observed opto-electronic behavior of the Al-doped samples. Interestingly, Shinde et al [22] reported that a similar blue shift observed in pulsed-laser deposited Al doped ZnO thin films disappeared upon annealing of the samples at 800°C.…”
Section: +mentioning
confidence: 83%
“…Different preparation methods such as coprecipitation [18], spray pyrolysis [19], sol-gel [20], hydrothermal routes [21], pulsed-laser deposition [22], and combustion [23] have been used. Some papers focus on the optical features of Al modified ZnO, indicating them as the key factors for the improved photocatalytic activity.…”
“…This occurrence, known as the Burstein-Moss effect [38], justifies the enhanced conductivity of these samples with respect to ZnO reported in literature [39] and explains the hereby observed opto-electronic behavior of the Al-doped samples. Interestingly, Shinde et al [22] reported that a similar blue shift observed in pulsed-laser deposited Al doped ZnO thin films disappeared upon annealing of the samples at 800°C.…”
Section: +mentioning
confidence: 83%
“…Different preparation methods such as coprecipitation [18], spray pyrolysis [19], sol-gel [20], hydrothermal routes [21], pulsed-laser deposition [22], and combustion [23] have been used. Some papers focus on the optical features of Al modified ZnO, indicating them as the key factors for the improved photocatalytic activity.…”
“…6 Therefore, increasing attention is drawn to fabricating superhydrophobic surfaces without any low energy organic materials, such as inorganic material lms with specic hierarchical rough surfaces. 15,16 However, few studies have reported how doping can affect the superhydrophobic properties of the surface. Recently, with the development of optoelectronic devices, the surface wettability of ZnO and its metal doping oxide has aroused great interest and been realized by combination of the micro-nanostructured topography and low surface energy.…”
This work reports on the systematic comparison of the crystalline structural, morphological and hydrophobic properties of ZnO and Al-doped ZnO (AZO) thin films fabricated by atomic layer deposition and the hydrothermal method. It was revealed that the surface wettability can be largely modified by Al doping in the zinc oxide film growth process. With Al doping, the morphology of the AZO films became more complex and rough. The water contact angle of a flower-like hierarchical ZnO film (123 AE 4 ) was improved by about 40 via Al doping to 160 AE 4 . We attributed the variation in surface hydrophobicity with Al doping to changes in the bond angle and distance between ZnO-H 2 O molecule. The computational simulations have been employed to verify the interfacial distinction between two main crystal orientations of AZO. This result suggests that Al doping can be considered a critical factor in changing the surface morphology of AZO as well as the hydrophobic properties. It is believed that the present route holds promise in the design and application of practical superhydrophobic materials.
“…The effect of band gap blue-shiing may be attributed to the Burstein-Moss effect, 31 which was already observed in previous studies of doped ZnO lms. 19,32,33 3.5. SKP-measurements SKP measurements with 10 minutes automated on/off illumination cycling are shown in Fig.…”
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.