Robust optoelectronic properties of PANI-Y2O3 nanocomposite as electron transport layer in OLEDs

Mandal, Gobind; Choudhary, R. N. P.; Kandulna, R.; Verma, Ajeet; Nayak, Debashish

doi:10.1063/5.0001153

Cited by 3 publications

(1 citation statement)

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“…)Where ∈ ′ -real part of the dielectric constant,∈ ′ = 𝐶 𝑝 𝑑 ∈ 0 𝐴 the imaginary part gives the dissipative energy means dielectricloss ∈ ″ = ∈ ′ tan (𝛿)= ∈ ′ D. Ac conductivity (𝜎 𝑎𝑐 = 𝑤 ∈ ′ tan (𝛿)) is also determined with the help of the real part and angular frequency. Here Cp-specific capacitance, D = tan ( 𝛿) loss factor.D -thickness, and A -area of the pellet[59,65]. All the necessary parameters were recorded from LCR meter and screw gauge meter.…”

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Thermal states of exfoliated gC3N4 embedded coral-shaped ZrO2 nanoparticles as a robust emissive layer for OLED application

Bauri

Choudhary

2022

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Metal-free graphitic carbon nitride (gC3N4) is proving as a growing star of the carbon nitride family due to its glamorous electrical, optical, and thermal properties. Blending of zirconium oxide (ZrO2) semiconductor with different weight percentage improves the properties of the pure gC3N4. In this work, we used the ultrasonic sound wave method to synthesize gC3N4/ZrO2 nanocomposite. Characterization techniques such as X-ray powder diffraction (XRD), field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HR-TEM), Fourier transforms infrared microscopy (FTIR), UV-visible, and photoluminescence were used to characterize the as-synthesized gC3N4, ZrO2, and gC3N4/ZrO2 nanocomposite. The XRD measurement method confirmed the crystalline nature and determined the average particle size of the composite. Fourier transform infrared (FTIR) spectroscopy was performed to examine the presence of functional groups in synthesized materials. Bandgap energy of 2.98 eV and light absorbed in the range of 250 nm - 450 nm was recorded by UV visible spectroscopy. Photoluminescence spectroscopy revealed photon emission in the range 450 nm -530 nm of the synthesized materials. Dielectric constant, refractive index (n=1.5), and electrical conductivity (2.63 × 10-3 S/cm) were computed using LCR meter and I-V graph. Lower dielectric constant, refractive index, optimized optical band gap energy, and higher electron-hole recombination rate of gC3N4/ZrO2illustrated a successful emissive layer for organic light-emitting diode applications.

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confidence: 99%