Raman spectroscopy method is used to study the influence of thermal and rf‐plasma treatments on structural changes in strongly damaged near‐surface layers in SiSiO2 structures implanted with P+ ions. The changes of the dimensions of the microcrystalline regions and the root mean square bond angle fluctuations of SiSi bonds in amorphized regions are evaluated. In addition, elastic energy and the relative contents of crystalline and amorphous phases in the implanted layers under such treatmens are evaluated. It is shown that the rf‐plasma treatment allows to obtain a totally relaxed Si amorphous structure.