Review on synthesis of ferrocene-based redox polymers and derivatives and their application in glucose sensing

Saleem, Muhammad; Yu, Haojie; Wang, Li; Zain‐ul‐Abdin,; Khalid, Hamad; Akram, Muhammad; Abbasi, Nasir M.; Huang, Jin

doi:10.1016/j.aca.2015.01.012

Cited by 136 publications

(78 citation statements)

References 168 publications

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“…Ferrocene derivatives with high optical absorptivity, good thermal and photochemical stability, ease of functionalization and favourable electrochemical properties have found many practical applications in materials science including catalysts, medicines, sensors, aerospace and electroactive materials …”

Section: Introductionmentioning

confidence: 99%

Derivatization of valproic acid using ferrocene derivatives: Synthesis, characterization and investigation of optical and electrochemical properties

Rahimpour

Jouyban

Teimuri‐Mofrad

2019

Applied Organom Chemis

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New ferrocenyl‐based valproic acid (VPA) ester derivatives were designed and synthesized according to the reaction of appropriate haloalkylferrocene derivatives with VPA in the presence of K2CO3 and a catalytic amount of 18‐crown‐6 ether. Elemental analyses and Fourier transform infrared, 1H NMR, 13C NMR and mass spectra all well confirmed the predicted molecular structure. This is the first report in which ferrocene has been applied in derivatization of VPA as a chromogenic group. The electrochemical properties of the synthesized compounds were studied using cyclic voltammetry measurements, and energies of the frontier molecular orbitals were determined. In addition, the solubilities of the final compounds were studied in distilled water, phosphate buffer (pH = 7.4) and 0.9% (w/v) NaCl solution.

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Section: Introductionmentioning

confidence: 99%

Derivatization of valproic acid using ferrocene derivatives: Synthesis, characterization and investigation of optical and electrochemical properties

Rahimpour

Jouyban

Teimuri‐Mofrad

2019

Applied Organom Chemis

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“…A number of polymeric systems have been shown to exhibit reversible changes in conformation or solubility in response to environmental changes, making these materials attractive for use in areas like drug delivery, analyte sensing, or tissue engineering . By selectively incorporating certain functional groups, such responsive materials can undergo a number of property changes as a result of external influences, including non‐chemical stimuli such as light or temperature, or through chemical stimuli such as changes in pH, redox reactions, or dynamic‐covalent, and supramolecular interactions . Photoresponsive materials often demonstrate reversible isomerization upon irradiation and commonly include materials with azobenzene moieties or spiropyrans .…”

Section: Introductionmentioning

confidence: 99%

Triple responsive block copolymers combining pH‐responsive, thermoresponsive, and glucose‐responsive behaviors

Brooks

Vancoillie

Kabb

et al. 2017

J. Polym. Sci. Part A: Polym. Chem.

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Polymers with multiple tunable responses were achieved by incorporating boronic acid functionality along the backbone of a thermoresponsive polymer. The inherent Lewis acidity and diol‐sensitivity of boronic acid moieties allowed these polymers to respond to changes in pH and glucose concentration. Through reversible addition‐fragmentation chain transfer copolymerization of boronic acid‐containing monomers with N‐isopropylacrylamide, well‐defined block copolymers were synthesized containing a hydrophilic N,N‐dimethylacrylamide block and a second, responsive block with temperature‐dependent water solubility, making the resulting polymers capable of self‐assembly into nanostructures upon heating. By incorporating boronic acids within the thermoresponsive block, the cloud point of the polymer depended on the solution conditions, including pH and diol concentration, allowing tunable cloud point ranges. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 2309–2317

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“…In the same year, Snegur et al published a review on antitumor activities of ferrocene derivatives which was followed by a review on ferrocene‐based peptides/amides . During 2013–2015, more specialized reviews appeared covering electrochemical aspects like ferrocene‐modified thin films and nanoparticles as biosensors, and synthesis and applications of ferrocene‐based redox polymer in glucose sensing …”

Section: Introductionmentioning

confidence: 99%

Recent advances in the synthesis, biological activities and various applications of ferrocene derivatives

Larik

Saeed

Fattah

et al. 2016

Applied Organom Chemis

123

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Ferrocene derivatives constitute an important class of organometallic compounds with not only an extensive range of biological activities but also diverse industrial as well as material science applications. These stimulating features of ferrocene derivatives spurred us to review the recent advances in synthesis methods and biological and other applications reported in the latest literature. An effort has been made to summarize the recent developments in synthetic methods providing access to ferrocene scaffolds and the useful medicinal and material applications, including agricultural, catalytic, polymer, conducting, redox mediating, ferrocenyl stationary phase, rocket propellant and ion sensing applications. Ferrocene‐based bulky metallocenes are also discussed.

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Review on synthesis of ferrocene-based redox polymers and derivatives and their application in glucose sensing

Cited by 136 publications

References 168 publications

Derivatization of valproic acid using ferrocene derivatives: Synthesis, characterization and investigation of optical and electrochemical properties

Derivatization of valproic acid using ferrocene derivatives: Synthesis, characterization and investigation of optical and electrochemical properties

Triple responsive block copolymers combining pH‐responsive, thermoresponsive, and glucose‐responsive behaviors

Recent advances in the synthesis, biological activities and various applications of ferrocene derivatives

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