Midâinfrared (MIR) fiber lasers have wide application prospects and great commercial value in the fields of medical operation, remote sensing and military weapon, etc. At present, Tm3+âdoped glass can obtain broadband luminescence at 2 Όm, the introduction of Ho3+ or Er3+ ions also shows a tunable MIR emission but with limited success. Herein, the rareâearth (RE) doped glass with quantum dots (QDs) precipitation is proposed for achieving ultraâbroadband MIR emissions. The types and sizes of QDs are determined by the XRD and TEM, and their optical properties are further characterized by the absorption and emission spectra as well as the lifetime decay curves. It is found that the diameter of the QDs is gradually increased from 1.7 to 5.1 nm by increasing the heatâtreated temperature from 490°C to 530°C, respectively. Interestingly, an ultraâbroadband emission covering 1400â2600 nm is achieved from the heatâtreated glass upon the excitation of 808 nm laser diode as a result of an overlapped emission from Tm3+ and PbS. All results suggest that these QDsâprecipitated REâdoped glasses have important application prospects in ultraâbroadband MIR laser glass, glass fiber, and fiber lasers.