Reverse ATRP of acrylonitrile with diethyl 2,3-dicyano-2,3-diphenyl succinate/FeCl3/iminodiacetic acid

Synthesis of poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) (PMMA-b-PNIPAM) amphiphilic diblock copolymer brushes on halloysite substrate via reverse ATRP

“…Secondly, some catalysts such as CuBr are unstable expose to the air and moisture. Therefore, a so-called reverse atom transfer radical polymerization (RATRP) has been developed rapid recently [11][12][13][14][15][16][17]. However, the preparation of welldefined polymer-grafted inorganic particles via RATRP is rarely reported yet [18][19][20].…”

Iron-based catalytic systems in atom-transfer controlled-radical-polymerization processes

“…The use of diethyl 2,3 dicyano 2,3 diphenylsuc cinate (DCDPS) as an initiator has practically no effect on the character of polymerization of AN in DMF with Fe(III) chloride based catalytic systems [111]. Iminodiacetic acid was used as an activator and complexing agent for FeCl 3 The initiator DCDPS may be used for the reverse ATRP mediated by the FeCl 3 /isophtalic acid system in DMF [112].…”

Emerging approaches to the surface modification of textiles

“…ATRP is a recently developed method for controlling radical polymerization (Zhou et al, 2008), and has been one of the most widely employed techniques, involving a fast dynamic equilibrium between dormant species and active radical species to provide control of the polymerization (Hou et al, 2006). It can achieve better control of polymer molecular weights, molecular weight distribution, and tolerances to various reaction conditions and can be applied to various monomers (Mittal et al, 2007).…”