Retro-crosslinking of cluster-based hybrid polymers

Dragan, Denise Silvia; Kogler, Franz René; Schubert, Ulrich

doi:10.1016/j.polymer.2007.12.012

Cited by 2 publications

(2 citation statements)

References 28 publications

(29 reference statements)

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“…The phenomenon of thermal stabilization of a compound by introducing inorganic nanoparticles or clusters was observed in various studies, such as the stabilization of organic polymers by introducing zirconium oxo clusters. 55 The increased thermal stability of the INN material in comparison to the pure bis-imidazolium tetrachlorocuprate complex allows the observation of the configuration change with temperature of the tetrachlorocuprate unit. As already described in the literature, tetrachlorocuprate complexes show a transition from square planar to tetragonal under thermal activation.…”

Section: Metal Complexation In Ionic Nanoparticle Networkmentioning

confidence: 99%

Ionic nanoparticle networks: development and perspectives in the landscape of ionic liquid based materials

2014

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This feature article gives an overview of the research performed on ionic nanoparticle networks (INNs). These INNs are hybrid materials consisting of inorganic nanoparticles and ionic linkers, such as imidazolium, bisimidazolium or pyridinium. The synthesis and properties of INNs, for catalysis or sensorics, are presented. At each step INN materials are compared to other hybrid materials of similar composition such as ionogels or suspensions of imidazolium modified nanoparticles.

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Section: Metal Complexation In Ionic Nanoparticle Networkmentioning

confidence: 99%

Ionic nanoparticle networks: development and perspectives in the landscape of ionic liquid based materials

2014

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“…8.8 and 4.4, respectively. 34 This shows that the clusters are connected by organic cords of strongly varying lengths.…”

Section: Structural Issues Of Cluster-crosslinked Polymersmentioning

confidence: 92%

Cluster-based inorganic–organic hybrid materials

2011

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Clusters as building blocks have been used for two types of inorganic-organic hybrid materials. The first are hybrid polymers, with polymer-like properties and structures, where the cluster units crosslink the polymer chains. They are prepared by co-polymerization of organic monomers with functional ligands attached to the clusters. The second type is crystalline metal-organic framework structures which are obtained by coordination chemistry approaches, i.e. by coordinating multifunctional organic ligands to cluster units. This tutorial review shows that both types of cluster-based materials are limiting cases with many options for varying both the cluster units as well as the connecting organic entities.

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Retro-crosslinking of cluster-based hybrid polymers

Cited by 2 publications

References 28 publications

Ionic nanoparticle networks: development and perspectives in the landscape of ionic liquid based materials

Ionic nanoparticle networks: development and perspectives in the landscape of ionic liquid based materials

Cluster-based inorganic–organic hybrid materials

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