Research Progress of the Solid State Lithium-Sulfur Batteries

Abstract

Lithium-sulfur batteries using lithium as the anode and sulfur as the cathode can achieve a theoretical energy density (2,600 Wh.g −1) several times higher than that of Li ion batteries based on the chemical conversion reaction of 6Li + S 8 ↔ 8Li 2 S. The cost effectiveness, together with the intrinsic high energy density of the Li-S batteries, enables it to be an important option for the next generation energy storage devices. However, lithium-sulfur batteries using the liquid electrolyte would lead to the dissolution and "shuttle effect" of polysulfides, which greatly decrease the cycle life and specific capacity. In order to realize long cycle life of the lithium-sulfur battery, it is crucial to address the uncontrolled diffusion of polysulfides. Replacing the liquid electrolyte with the solid electrolyte, which can address the polysulfide dissolution and diffusion problem, inhibit the growth of lithium dendrites on the anode side, and greatly improve the safety and the cycle stability of lithium-sulfur batteries. In spite of the above merits, the performance and application of solid state Li-S batteries are strongly constrained by their low discharge capacity, poor rate performance and unsatisfied cycle life, which need to be overcome by advances in both the materials and the battery design. In this mini-review, the recent research progress of solid-state lithium-sulfur batteries in several aspects, including the sulfur-cathode design, different types of solid electrolyte and Li-S batteries based on them is described/summarized. New insights and synthesis approaches for the stable lithium anode are also summarized. We particularly emphasize the role of the interface in impeding the battery reaction, as well as the construction of the "solid/solid/solid" three-phase reaction boundary. At last, the prospects and challenges in further advancing the scientific understanding and enabling the battery technology viable are presented to shed light on the upcoming research efforts.

Electrochemical Impedance Spectroscopy for All‐Solid‐State Batteries: Theory, Methods and Future Outlook

“…In addition, these improvements could aid in the development of all-solid-state LiÀ S and Li-air technologies that harness SPEs. Despite the fact that there are examples of SPEs being employed in these systems, [163,164] there are limited reports of full cell EIS. [165][166][167][168] In agreement with Section 4, LiÀ S cells with a SPE have a highfrequency impedance contribution from the electrolyte, followed by the anode and lastly the cathode impedance.…”

Interface Aspects in All‐Solid‐State Li‐Based Batteries Reviewed

“…These materials showed better conductive properties, which facilitates to establish a low‐resistance at the cathode/solid–electrolyte interface. [ 193 ]…”

Roadmap of Solid-State Lithium-Organic Batteries toward 500 Wh kg–1

“…Considering the fact that the flexible nature of OBEMs resembles the one of sulfur to some extent, some approaches in Li–sulfur batteries are potentially applicable to organic ASSBs with oxide electrolytes . Xu et al coated carbon nanotubes on a three-dimensional garnet framework to build a mixed electron/ion conducting host for active materials (Figure c).…”

“…Considering the fact that the flexible nature of OBEMs resembles the one of sulfur to some extent, some approaches in Li−sulfur batteries are potentially applicable to organic ASSBs with oxide electrolytes. 147 Xu et al 146 coated carbon nanotubes on a three-dimensional garnet framework to build a mixed electron/ion conducting host for active materials (Figure 5c). The approach has enabled successful cycling of Li−sulfur battery in the garnet electrolyte, where sulfur was infused into the porous structure with adequate electron/ion percolation.…”