“…Vanadium is a toxic heavy metal, widely used across am ultitude of industries-smelting, foundry,t extile, ceramic, glass, and refinery to name af ew. [1,2] Vanadium can mostly be foundi nt hree oxidation states, + 3, + 4a nd + 5, with multiple species co-existing across the pH and potential (E H )l andscape. [3] Under most conditions vanadium(V)o ccurs as vanadate(V) oxyanion (H 2 VO 3 À / HVO 4 2À ), whereas the oxycation of the same oxidation state (VO 2 + )c an form under highly acidic conditions.…”