Removal of selected pharmaceuticals and personal care products (PPCPs) and endocrine-disrupting chemicals (EDCs) during sand filtration and ozonation at a municipal sewage treatment plant

Nakada, Norihide; Shinohara, Hiroyuki; Murata, Ayako; Kiri, Kentaro; Managaki, Satoshi; Sato, Nobuyuki; Takada, Hideshige

doi:10.1016/j.watres.2007.06.038

Cited by 522 publications

(231 citation statements)

References 29 publications

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“…In river water sample, concentration of E1, E2 and EE2 were changed from nd to 74 ng/l in United Kingdom (Fawell et al 2001), Italy (Baronti et al 2000) and China (Chen et al 2007). In effluent of WWTPs, common detected value were nd to 82, nd to 64, nd to 42 and 0.4 to 39.1 ng/lfor E1, E2, EE2 and E3 in Netherlands (Vethaak et al 2005), Italy (Baronti et al 2000), U.K. (Desbrow et al 1998;Johnson and Sumpter 2001), Germany and Canada (Ternes et al 1999), Sweden (Larsson et al 1999), Japan (Nakada et al 2007) and China (Wang et al 2005;Chen et al 2007;Sun et al 2008). Our results in this study were within the range of previous report.…”

Section: Methods Performancesupporting

confidence: 86%

An alternative method for the determination of estrogens in surface water and wastewater treatment plant effluent using pre-column trimethylsilyl derivatization and gas chromatography/mass spectrometry

Zhou

et al. 2008

Environ Monit Assess

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A procedure using pre-column trimethylsilyl derivatization and gas chromatography/ mass spectrometry (GC/MS) was developed and applied in determining trace estrogens in complex matrix. Main conditions were optimized, including pH value, salinity of water sample, elution reagents, clean procedure, derivative solvent and temperature. The optimized method was used to determine steroid estrogens in surface water and effluents of wastewater treatment plant (WWTP). Low detection limits of 0.01, 0.03, 0.03, 0.07, 0.09 and 0.13 ng/l for DES, E1, E2, EE2, E3 and E V , respectively were obtained under optimism condition. No apparent interferences appeared in chromatography in comparison with ultrapure water blank. Mean recovery ranged from 72.6% to 111.0% with relative standard deviation of

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Section: Methods Performancesupporting

confidence: 86%

An alternative method for the determination of estrogens in surface water and wastewater treatment plant effluent using pre-column trimethylsilyl derivatization and gas chromatography/mass spectrometry

Zhou

et al. 2008

Environ Monit Assess

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“…34,40,52,71,72 Similar to observations with MBRs, available data indicate a slight increase in the extent of PPCP removal when sand filtration is used for post-secondary treatment (Fig. 6).…”

Section: B1 Membrane Bioreactors (Mbrs)supporting

confidence: 72%

Pharmaceuticals and personal care products in effluent matrices: A survey of transformation and removal during wastewater treatment and implications for wastewater management

2010

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“…Through the strong oxidative properties of ozone and of the hydroxyl radicals produced spontaneously in its decomposition, ozonation was found to degrade efficiently most micropollutants present in treated wastewater with a dose of 3-8 mg O 3 l -1 Nakada et al, 2007;Reungoat et al, 2012;Reungoat et al, 2010;Rosal et al, 2010). A potential disadvantage of this process is the formation of unknown reactive by-products due to partial oxidation of the compounds and reaction with matrix components (von Gunten, 2003a).…”

Section: Introductionmentioning

confidence: 99%

Treatment of micropollutants in municipal wastewater: Ozone or powdered activated carbon?

Margot

Kienle

Magnet³

et al. 2013

Science of The Total Environment

677

404

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Highlights• Micropollutants are efficiently removed by both ozone and powdered activated carbon• Specific substances were removed more efficiently by ozone• Powdered activated carbon effectively removed a wider range of pollutants• Both treatments significantly reduced the toxicity of WWTP effluent AbstractMany organic micropollutants present in wastewater, such as pharmaceuticals and pesticides, are poorly removed in conventional wastewater treatment plants (WWTPs). To reduce the release of these substances into the aquatic environment, advanced wastewater treatments are necessary. In this context, two large-scale pilot advanced treatments were tested in parallel over more than one year at the municipal WWTP of Lausanne, Switzerland. The treatments were: i) oxidation by ozone followed by sand filtration (SF) and ii) powdered activated carbon (PAC) adsorption followed by either ultrafiltration (UF) or sand filtration. More than 70 potentially problematic substances (pharmaceuticals, pesticides, endocrine disruptors, drugs metabolites and other common chemicals) were regularly measured at different stages of treatment. Additionally, several ecotoxicological tests such as the yeast estrogen screen, a combined algae bioassay and a fish early life stage test were performed to evaluate effluent toxicity. Both treatments significantly improved the effluent quality. Micropollutants were removed on average over 80% compared with raw wastewater, with an average ozone dose of 5.7 mg O 3 l -1 or a PAC dose between 10 and 20 mg l -1 . Depending on the chemical properties of the substances (presence of electron-rich moieties, charge and hydrophobicity), either ozone or PAC performed better. Both advanced treatments led to a clear reduction in toxicity of the effluents, with PAC-UF performing slightly better overall. As both treatments had, on average, relatively similar efficiency, further criteria relevant to their implementation were considered, including local constraints (e.g., safety, sludge disposal, disinfection), operational feasibility and cost. For sensitive receiving waters (drinking water resources or recreational waters), the PAC-UF treatment, despite its current higher cost, was considered to be the most suitable option, enabling good removal of most micropollutants and macropollutants without forming problematic by-products, the strongest decrease in toxicity and a total disinfection of the effluent.

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Removal of selected pharmaceuticals and personal care products (PPCPs) and endocrine-disrupting chemicals (EDCs) during sand filtration and ozonation at a municipal sewage treatment plant

Cited by 522 publications

References 29 publications

An alternative method for the determination of estrogens in surface water and wastewater treatment plant effluent using pre-column trimethylsilyl derivatization and gas chromatography/mass spectrometry

An alternative method for the determination of estrogens in surface water and wastewater treatment plant effluent using pre-column trimethylsilyl derivatization and gas chromatography/mass spectrometry

Pharmaceuticals and personal care products in effluent matrices: A survey of transformation and removal during wastewater treatment and implications for wastewater management

Treatment of micropollutants in municipal wastewater: Ozone or powdered activated carbon?

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