Reliability of Sn–8 mass%Zn–3 mass%Bi Lead-Free Solder and Zn Behavior

Abstract

In order to evaluate the reliability of Sn-8 mass%Zn-3 mass%Bi (hereafter, Sn-8Zn-3Bi) solder, thermal shock tests (temperature range: from 233 to 353 K) and high temperature humidity tests (test condition: 353 K, 85% relative humidity) were conducted. The PCB (Printed Circuit Board) pads were finished by OSP (Organic Solderability Preservative), Sn and Ni/Au. The electric part for test was QFP (Quad Flat Package), and the lead was plated by Sn-3 mass%Bi. The joint strength was estimated by pull testing, and Zn-phase behavior in solder joint was examined.The pull strengths of Sn-8Zn-3Bi joints in the as-soldered state were measured to be about 16N, irrespective of the PCB pad coatings. After thermal shock testing (hereafter, TS test) up to 1000 cycles, the pull strengths decreased to around 14N. Meanwhile, after high temperature humidity testing (hereafter, HTH test) up to 1000 h, the pull strengths deceased to around 6N, irrespective of the PCB pad coatings. The reason for the drastic decrease of pull strength after the HTH test was proven to be a crack that was observed along the zinc oxide-phase. The Zn-phase in the Sn-8Zn-3Bi solder changed from a separate acicular shape to a lined-up branched arrangement after HTH tests of 1000 h.

Effects of Ag and Cu addition on microstructural properties and oxidation resistance of Sn–Zn eutectic alloy

“…The oxidation distance was measured to be approximately 10 m for Sn-9Zn-2Ag alloys and 30 m for Sn-9Zn-4Cu alloys. It is known that the oxidation resistance of the Sn-Zn eutectic and Sn-8Zn-3Bi pastes is poor for the joining of QFP or 1608R chips to Cu electrodes during thermal and humidity exposure [18,28]. According to recent reports [18], the oxidation rate of the Sn-Zn eutectic alloy is much slower than that of the Sn-8Zn-3Bi alloy under the same conditions; the oxidation distance is 70 and 130 m after 1000 h exposure, respectively.…”