Release of Graphene and Carbon Nanotubes from Biodegradable Poly(Lactic Acid) Films during Degradation and Combustion: Risk Associated with the End-of-Life of Nanocomposite Food Packaging Materials

Abstract

Nanoparticles of graphene and carbon nanotubes are attractive materials for improvement of mechanical and barrier properties and functionality of biodegradable polymers for food packaging applications. However, the increase of the manufacture and consumption increases the probability of exposure of human and environment to such nanomaterials, this rising questions about the risks of nanomaterials since they can be toxic. For a risk assessment, it is crucial to know whether airborne nanoparticles of graphene and carbon nanotubes can be released from nanocomposites into the environment at their end-life, or they remain embedded in the matrix. In this work the release of graphene and carbon nanotubes from the poly(lactic) acid nanocomposite films were studied for the scenarios of: (i) biodegradation of matrix polymer at the disposal of wastes; and (ii) combustion and fire of nanocomposite wastes. Thermogravimetric analysis in air atmosphere, TEM, AFM and SEM were used to verify the release of nanoparticles from nanocomposite films. The three factors model was applied for the quantitative and qualitative risk assessment to the release of graphene and carbon nanotubes from nanocomposite wastes for these scenarios. Safety concern is discussed in respect to the existing regulations for nanowastes stream.

Biodegradable Poly(Lactic Acid) Nanocomposites for Fused Deposition Modeling 3D Printing

“…Another concern, especially with carbon-based additives, is that the degradation byproducts contain hazardous particles. However, a study by Ivanov et al indicates that PLA/carbon nanocomposites biodegrade into safe byproducts under standard degradation conditions [ 11 , 75 , 76 , 77 ].…”